Fe(tetraphenylporphyrin)F

Base Information

• Chemical Name: Fe(tetraphenylporphyrin)F
• CAS No.: 55428-47-2
• Molecular Formula: C₄₄H₂₈FFeN₄
• Molecular Weight: 687.579
• Mol file: 55428-47-2.mol

Synonyms:Fe(tetraphenylporphyrin)F

Chemical Property of Fe(tetraphenylporphyrin)F

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Fe(tetraphenylporphyrin)F

There total 5 articles about Fe(tetraphenylporphyrin)F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + iron(III) fluoride trihydrate → (TPP)FeF (55428-47-2)

Guidance literature:

In N,N-dimethyl-formamide; educts in a molar ratio ca. 1:2 in dild. DMF (dry) soln. were refluxed for 6 h; most of the solvent removed, the residue crystd. overnight; complex filtered, washed with EtOH, recrystd. from CH2Cl2/cyclohexane; elem. anal.;

DOI:10.1016/S0277-5387(00)81058-X

Reference yield:

(TPP)FeF2 (115825-94-0) → Fe(tetraphenylporphyrin)F (55428-47-2) + (TPP)Fe(F)(O) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

With water; In dichloromethane; rapid reaction even at low temp.;;

DOI:10.1021/ja00227a019

Reference yield:

((5,10,15,20-tetraphenylporphyrinato)iron(III))2O (12582-61-5) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → Fe(tetraphenylporphyrin)F (55428-47-2)

Guidance literature:

In dichloromethane; water; equilibration with HF in a teflon container;; concn. with addn. of heptane;;

DOI:10.1021/ja00227a019

upstream raw materials:

((5,10,15,20-tetraphenylporphyrinato)iron(III))2O

hydrogen fluoride

(TPP)FeF₂

{(TPP)Fe}2O(ClO₄)2

Downstream raw materials:

terabutylammonium difluoro(tetraphenylporphyrinato)ferrate(III)

(TPP)FeF₂^(1-)