(4-(Nonyloxy)phenyl)boronic acid

Base Information

• Chemical Name: (4-(Nonyloxy)phenyl)boronic acid
• CAS No.: 173392-87-5
• Molecular Formula: C15H25BO3
• Molecular Weight: 264.173
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID00400723
• Nikkaji Number: J1.913.026F
• Wikidata: Q82203741
• Mol file: 173392-87-5.mol

Synonyms:173392-87-5;(4-(Nonyloxy)phenyl)boronic acid;4-(N-Nonyloxy)phenylboronic acid;(4-nonoxyphenyl)boronic Acid;4-(n-Nonyloxy)benzeneboronic acid;[4-(Nonyloxy)phenyl]boronic acid;(4-(Nonyloxy)phenyl)boronicacid;4-Nonyloxyphenylboronic acid;SCHEMBL7472946;DTXSID00400723;XAJSPPCQRRBXGB-UHFFFAOYSA-N;YGA39287;MFCD04039033;AKOS004116288;BS-21719;Boronic acid,[4-(nonyloxy)phenyl]-(9ci);CS-0174660;FT-0747605;F77561;A881774

Chemical Property of (4-(Nonyloxy)phenyl)boronic acid

Chemical Property:

• Vapor Pressure: 2.11E-07mmHg at 25°C
• Refractive Index: 1.5
• Boiling Point: 408.4 °C at 760 mmHg
• Flash Point: 200.8 °C
• PSA: 49.69000
• Density: 1.01 g/cm³
• LogP: 2.49580
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 10
• Exact Mass: 264.1896748
• Heavy Atom Count: 19
• Complexity: 204

Purity/Quality:

99%min ^*data from raw suppliers

4-(n-Nonyloxy)benzeneboronic acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=CC=C(C=C1)OCCCCCCCCC)(O)O

Technology Process of (4-(Nonyloxy)phenyl)boronic acid

There total 5 articles about (4-(Nonyloxy)phenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-bromo-4-(nonyloxy)benzene (105100-90-1) → p-nonyloxyphenylboronic acid (173392-87-5)

Guidance literature:

1-bromo-4-(nonyloxy)benzene; With n-butyllithium; Trimethyl borate;

With hydrogenchloride;

DOI:10.1080/10587250108025293

Reference yield:

Trimethyl borate (121-43-7,63156-11-6) + 1-bromo-4-(nonyloxy)benzene (105100-90-1) → p-nonyloxyphenylboronic acid (173392-87-5)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane;

Reference yield:

1-bromo-4-(nonyloxy)benzene (105100-90-1) → p-nonyloxyphenylboronic acid (173392-87-5) + 2,4,6-tris-(4-nonyloxy-phenyl)-cyclotriboroxane

Guidance literature:

1-bromo-4-(nonyloxy)benzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.75h;

With Trimethyl borate; In tetrahydrofuran; at -78 ℃; for 1h;

With hydrogenchloride; at 20 ℃; for 1h;

DOI:10.1080/15421400390223158

upstream raw materials:

1-bromo-4-(nonyloxy)benzene

4-bromo-phenol

1-Bromononane

Trimethyl borate

Downstream raw materials:

1,4-bis(4-nonyloxyphenyl)-6,7-dimethylanthraquinone

Refernces

• 1、 Marson,Farrand,Brettle,Dunmur. "Highly efficient syntheses of 3-aryl-2-cycloalken-1-ones and an evaluation of their liquid crystalline properties". . p. 4377 - 4381. Retrieved 2007/10/03.
• 2、 Belloni, Maura,Manickam,Wang, Zehn-He,Preece, Jon A.. "Toward boronate ester mesogenic structures". . p. 93 - 114. Retrieved 2007/10/03.