N-(2,6-dimethylphenyl)-N-{3-[(2,6-dimethylphenyl)imino]-1-methylbutylidene}amine

Base Information

• Chemical Name: N-(2,6-dimethylphenyl)-N-{3-[(2,6-dimethylphenyl)imino]-1-methylbutylidene}amine
• CAS No.: 213130-55-3
• Molecular Formula: C₂₁H₂₆N₂
• Molecular Weight: 306.451
• Mol file: 213130-55-3.mol

Synonyms:1,5-bis(2,6-dimethylphenyl)-2,4-pentanediimine

Chemical Property of N-(2,6-dimethylphenyl)-N-{3-[(2,6-dimethylphenyl)imino]-1-methylbutylidene}amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2,6-dimethylphenyl)-N-{3-[(2,6-dimethylphenyl)imino]-1-methylbutylidene}amine

There total 2 articles about N-(2,6-dimethylphenyl)-N-{3-[(2,6-dimethylphenyl)imino]-1-methylbutylidene}amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2,6-dimethylaniline (87-62-7) + acetylacetone (123-54-6,81235-32-7) → 1,5-bis(2,6-dimethylphenyl)-2,4-pentanediimine (213130-55-3)

Guidance literature:

With toluene-4-sulfonic acid; In benzene; for 24h; Schlenk technique; Inert atmosphere; Reflux;

DOI:10.1016/j.apcata.2012.09.024

Reference yield:

C33H36CuN3 → 1,5-bis(2,6-dimethylphenyl)-2,4-pentanediimine (213130-55-3) + N-nitrosodiphenylamine (382165-80-2,86-30-6)

Guidance literature:

With nitrogen(II) oxide; In benzene-d6; Inert atmosphere;

DOI:10.1002/anie.200905171

Reference yield: 82.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + 1,5-bis(2,6-dimethylphenyl)-2,4-pentanediimine (213130-55-3) → C21H25N2O3S(1-)*Li(1+)*C4H8O

Guidance literature:

tetrahydrofuran; 1,5-bis(2,6-dimethylphenyl)-2,4-pentanediimine; With n-butyllithium; In hexane; at -78 - 20 ℃; for 0.75h; Schlenk technique; Inert atmosphere;

With sulfur trioxide trimethylamine complex; In hexane; at -78 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.organomet.7b00397

upstream raw materials:

2,6-dimethylaniline

acetylacetone

Downstream raw materials:

((CH₃)2C₆H₃NCCH₃)2CHFeN(Si(CH₃)3)2

C₂₁H₂₄Br₂N₂Si

C₂₁H₂₃Br₅N₂Si₂

BrH*C₂₁H₂₆N₂