Methyl 4-(3-formylphenyl)benzoate

Base Information

Chemical Name:Methyl 4-(3-formylphenyl)benzoate
CAS No.:221021-36-9
Molecular Formula:C15H12O3
Molecular Weight:240.258
Hs Code.:2918300090
European Community (EC) Number:623-835-8
DSSTox Substance ID:DTXSID90401901
Nikkaji Number:J1.042.487I
Wikidata:Q82205200
Mol file:221021-36-9.mol

Synonyms:221021-36-9;Methyl 4-(3-formylphenyl)benzoate;3'-Formylbiphenyl-4-carboxylic acid methyl ester;Methyl 3'-formyl-[1,1'-biphenyl]-4-carboxylate;Methyl 3'-formyl[1,1'-biphenyl]-4-carboxylate;methyl 3'-formylbiphenyl-4-carboxylate;SCHEMBL881425;DTXSID90401901;AQDLVJIWBSWMFZ-UHFFFAOYSA-N;WIA02136;MFCD04039122;AKOS004114083;BS-23615;Methyl 4-(3-formylphenyl)benzoate, 97%;4-(3-Formylphenyl)benzoic acid methyl ester;BB 0222592;CS-0204705;Methyl3'-formyl-[1,1'-biphenyl]-4-carboxylate;J-014500

Suppliers and Price of Methyl 4-(3-formylphenyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3''-Formylbiphenyl-4-carboxylicAcidMethylEster
100mg
$ 60.00

TRC
3''-Formylbiphenyl-4-carboxylicAcidMethylEster
50mg
$ 45.00

Sigma-Aldrich
Methyl 4-(3-formylphenyl)benzoate 97%
1g
$ 89.80

Crysdot
Methyl3'-formyl-[1,1'-biphenyl]-4-carboxylate 95+%
10g
$ 425.00

American Custom Chemicals Corporation
3'-FORMYLBIPHENYL-4-CARBOXYLIC ACID METHYL ESTER 95.00%
1G
$ 708.48

Alichem
Methyl3'-formyl-[1,1'-biphenyl]-4-carboxylate
10g
$ 400.00

AK Scientific
Methyl3'-formyl[1,1'-biphenyl]-4-carboxylate
5g
$ 310.00

AK Scientific
Methyl3'-formyl[1,1'-biphenyl]-4-carboxylate
250mg
$ 29.00

Total 13 raw suppliers

Chemical Property of Methyl 4-(3-formylphenyl)benzoate

Chemical Property:

Melting Point:97-101 °C
Boiling Point:402.4 °C at 760 mmHg
Flash Point:180 °C
PSA：43.37000
Density:1.176 g/cm³
LogP:2.95270
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:240.078644241
Heavy Atom Count:18
Complexity:292

Purity/Quality:

98%,99%, ^*data from raw suppliers

3''-Formylbiphenyl-4-carboxylicAcidMethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi, N
Hazard Codes:N,Xi
Statements: 50/53
Safety Statements: 60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C2=CC=CC(=C2)C=O

Technology Process of Methyl 4-(3-formylphenyl)benzoate

There total 4 articles about Methyl 4-(3-formylphenyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 3132-99-8
m-bromobenzoic aldehyde

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 221021-36-9
methyl 3’-formyl-[1,1’-biphenyl]-4-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In water; acetonitrile; at 90 ℃; for 18h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;

Reference yield:

: 222180-23-6
3’-formyl-[1,1’-biphenyl]-4-carboxylic acid

: 74-88-4
methyl iodide

: 221021-36-9
methyl 3’-formyl-[1,1’-biphenyl]-4-carboxylate

Guidance literature:: In N,N-dimethyl-formamide; at 20 ℃; for 2h;

Reference yield:

: 3132-99-8
m-bromobenzoic aldehyde

: 221021-36-9
methyl 3’-formyl-[1,1’-biphenyl]-4-carboxylate

Guidance literature:: With sodium methylate; lithium chloride; Palladacycle; Yield given; Multistep reaction; 1.) NMP, 90 deg C; 2.) THF, MeOH, reflux, 12 h;
DOI:10.1016/S0040-4039(98)02384-3