2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

Base Information

Chemical Name:2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde
CAS No.:126087-78-3
Molecular Formula:C₂₁H₂₈OS
Molecular Weight:328.519
Hs Code.:

Synonyms:2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

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Chemical Property of 2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

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Technology Process of 2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

There total 2 articles about 2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 126113-04-0
1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

: 126087-78-3
2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -80 ℃; for 0.5h;

Reference yield:

: 114701-17-6,116512-58-4
trans-2-<(phenylthio)methylene>-5,5,8a-trimethylperhydro-1(2H)-naphthalenone

: 126087-78-3
2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / ZnI₂ / CH₂Cl₂ / 1 h / Ambient temperature

2: 75 percent / DIBAL / toluene; CH₂Cl₂ / 0.5 h / -80 °C

With diisobutylaluminium hydride; zinc(II) iodide; In dichloromethane; toluene;

Reference yield:

: 126087-78-3
2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

: 1811-23-0,69779-99-3,123809-45-0
(+/-)-confertifolin

Guidance literature:: Multi-step reaction with 3 steps

1: sodiumperiodate / methanol; acetonitrile; H₂O / 36 h / Ambient temperature

2: 1.) 2,6-lutidine, trifluoroacetic anhydride, 2.) aq. KOH / 1.) CH₂Cl₂, room tempearture, 1 h, 2.) 30 min

3: 78 percent / mercury(II) chloride, aq. H₂SO₄ / ethanol / 16 h / 70 °C

With 2,6-dimethylpyridine; potassium hydroxide; sodium periodate; sulfuric acid; trifluoroacetic anhydride; mercury dichloride; In methanol; ethanol; water; acetonitrile;