1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

Base Information

Chemical Name:1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen
CAS No.:126113-04-0
Molecular Formula:C₂₄H₃₅NOSSi
Molecular Weight:413.7
Hs Code.:

Synonyms:1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

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Chemical Property of 1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

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Technology Process of 1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

There total 1 articles about 1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 7677-24-9
trimethylsilyl cyanide

: 114701-17-6,116512-58-4
trans-2-<(phenylthio)methylene>-5,5,8a-trimethylperhydro-1(2H)-naphthalenone

: 126113-04-0
1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

Guidance literature:: With zinc(II) iodide; In dichloromethane; for 1h; Ambient temperature;

Reference yield: 75.0%

: 126113-04-0
1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

: 126087-78-3
2-phenylthiomethyl-5,5,8αβ-trimethyl-trans-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxaldehyde

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -80 ℃; for 0.5h;

Reference yield:

: 126113-04-0
1-cyano-2-(phenylthiomethylene)-5,5,8αβ-trimethyl-1-trimethylsilyloxy-trans-perhydronaphthalen

: 1811-23-0,69779-99-3,123809-45-0
(+/-)-confertifolin

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / DIBAL / toluene; CH₂Cl₂ / 0.5 h / -80 °C

2: sodiumperiodate / methanol; acetonitrile; H₂O / 36 h / Ambient temperature

3: 1.) 2,6-lutidine, trifluoroacetic anhydride, 2.) aq. KOH / 1.) CH₂Cl₂, room tempearture, 1 h, 2.) 30 min

4: 78 percent / mercury(II) chloride, aq. H₂SO₄ / ethanol / 16 h / 70 °C

With 2,6-dimethylpyridine; potassium hydroxide; sodium periodate; sulfuric acid; diisobutylaluminium hydride; trifluoroacetic anhydride; mercury dichloride; In methanol; ethanol; dichloromethane; water; toluene; acetonitrile;