[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

Base Information

Chemical Name:[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate
CAS No.:1611459-83-6
Molecular Formula:C₂₁H₂₄O₅
Molecular Weight:356.419
Hs Code.:

Synonyms:[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

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Chemical Property of [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

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Technology Process of [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

There total 7 articles about [(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1611459-80-3
(2R,3R)-3-(benzyloxy)-2,4-dihydroxybutyl benzoate

: 77-76-9
2,2-dimethoxy-propane

: 1611459-83-6
[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.tetasy.2014.04.002

Reference yield:

: 1611459-82-5
C₁₈H₁₈O₅

: 1611459-83-6
[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / methanol; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

With sodium tetrahydroborate; toluene-4-sulfonic acid; In methanol; dichloromethane;
DOI:10.1016/j.tetasy.2014.04.002

Reference yield:

: 34370-91-7,59358-33-7,68354-70-1,70798-12-8,19139-80-1
3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose

: 1611459-83-6
[(4'R,5'R)-5'-(benzyloxy)-2',2'-dimethyl-1',3'-dioxan-4'-yl]methyl benzoate

Guidance literature:: Multi-step reaction with 5 steps

1: dmap; pyridine / 1.67 h / 0 - 20 °C / Inert atmosphere

2: trifluoroacetic acid / water / 6 h / 0 °C / Inert atmosphere

3: sodium periodate / methanol; water / 1 h / 20 °C / Inert atmosphere

4: sodium tetrahydroborate / methanol; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

5: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

With pyridine; dmap; sodium tetrahydroborate; sodium periodate; toluene-4-sulfonic acid; trifluoroacetic acid; In methanol; dichloromethane; water;
DOI:10.1016/j.tetasy.2014.04.002