5,5-dimethyl-2-phenylsulfanylcyclohexanone

Base Information

Chemical Name:5,5-dimethyl-2-phenylsulfanylcyclohexanone
CAS No.:123257-46-5
Molecular Formula:C₁₄H₁₈OS
Molecular Weight:234.362
Hs Code.:

Synonyms:5,5-dimethyl-2-phenylsulfanylcyclohexanone

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Chemical Property of 5,5-dimethyl-2-phenylsulfanylcyclohexanone

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Technology Process of 5,5-dimethyl-2-phenylsulfanylcyclohexanone

There total 3 articles about 5,5-dimethyl-2-phenylsulfanylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 2979-19-3
3,3-dimethylcyclohexanone

: 882-33-7
diphenyldisulfane

: 123257-46-5
5,5-dimethyl-2-phenylsulfanylcyclohexanone

Guidance literature:: 3,3-dimethylcyclohexanone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

diphenyldisulfane; With boron trifluoride diethyl etherate; In tetrahydrofuran; at 20 ℃; for 2.5h;
DOI:10.1021/jo060077r

Reference yield:

: 1193-18-6
3-methylcyclohexen-2-one

: 123257-46-5
5,5-dimethyl-2-phenylsulfanylcyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: CuI / tetrahydrofuran / -78 - 20 °C

1.2: 61 percent / BF₃*Et₂O / tetrahydrofuran / 2.5 h / 20 °C

2.1: LDA / tetrahydrofuran / 1 h / -78 °C

2.2: 65 percent / BF₃*Et₂O / tetrahydrofuran / 2.5 h / 20 °C

With copper(l) iodide; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/jo060077r