Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

Base Information

Chemical Name:Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))
CAS No.:849060-35-1
Molecular Formula:C₃₈H₅₁AlN₂O₃
Molecular Weight:610.816
Hs Code.:

Synonyms:Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

Chemical Property:

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Technology Process of Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

There total 3 articles about Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 97-93-8
triethylaluminum

: 103595-81-9
N,N′-bis(3,5-di-t-butylsalicylidene)-ethylenediamine

: 108-95-2,27073-41-2
phenol

: 849060-35-1
[N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediimine]aluminum(III) phenoxide

Guidance literature:: In toluene; AlEt3 and (t-Bu)salenH2 in toluene was stirred under reflux for 1 h, cooled and stirred at room temp. for 1 h, phenol was added and stirred for 1 h; soln. was concd., hexane was added, ppt. was filtered, dried under vac.;
DOI:10.1021/ic048508g

Reference yield: 64.0%

: 190370-33-3
(Bu(t)4salen)AlMe

: 108-95-2,27073-41-2
phenol

: 849060-35-1
Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

Guidance literature:: In toluene; at 110 ℃;
DOI:10.1039/c8cc01528g

Reference yield:

: 103595-81-9
N,N′-bis(3,5-di-t-butylsalicylidene)-ethylenediamine

: 849060-35-1
Al(phenolato)(N,N'-bis(3,5-di-tert-butylsalicylidene)-ethylenediamine(-2H))

Guidance literature:: Multi-step reaction with 2 steps

1: toluene / 1 h / -78 - 110 °C / Schlenk technique; Glovebox; Inert atmosphere

2: toluene / 110 °C

In toluene;
DOI:10.1039/c8cc01528g