p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Base Information

Chemical Name:p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede
CAS No.:1269466-85-4
Molecular Formula:C₃₃H₄₂O₆SSi
Molecular Weight:594.844
Hs Code.:

Synonyms:p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Suppliers and Price of p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

There total 9 articles about p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside

: 1269466-85-4
p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; diborane; In tetrahydrofuran; dichloromethane; at 0 ℃; for 1.5h; Inert atmosphere;
DOI:10.1021/acs.orglett.5b02185

Reference yield: 95.0%

: 1269466-82-1
p-methylphenyl 2-O-benzoyl-4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-1-thio-β-D-galactoside

: 1269466-85-4
p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Guidance literature:: With borane-THF; trimethylsilyl trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane; at 0 ℃; for 5h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol200192d

Reference yield:

: p-methylphenyl 2-O-benzoyl-3,4-O-benzylidene-1-thio-β-D-galactopyranoside

: 1269466-85-4
p-tolyl 2-O-benzoyl-3-O-tert-butyldimethylsilyl-4-O-benzyl-1-thio-β-D-galactopyranosidede

Guidance literature:: Multi-step reaction with 3 steps

1: camphor-10-sulfonic acid / acetonitrile / 8 h / 20 °C

2: 1H-imidazole / dichloromethane / 3 h / 20 °C / Inert atmosphere

3: borane-THF; trimethylsilyl trifluoromethanesulfonate / tetrahydrofuran; dichloromethane / 5 h / 0 °C / Inert atmosphere

With 1H-imidazole; borane-THF; trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; In tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1021/ol200192d