056-(FERROCENYL)HEXANETHIOL

Base Information

• Chemical Name: 056-(FERROCENYL)HEXANETHIOL
• CAS No.: 134029-92-8
• Molecular Formula: C₁₆H₂₂FeS
• Molecular Weight: 302.264
• Hs Code.: 29309090
• Mol file: 134029-92-8.mol

Synonyms:(6-Mercaptohexyl)ferrocene;6-Ferrocenyl-1-hexanethiol;6-Ferrocenylhexanethiol;

Chemical Property of 056-(FERROCENYL)HEXANETHIOL

Chemical Property:

• Boiling Point: 321-353 °C
• PSA: 38.80000
• LogP: 4.29100
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

100% ^*data from raw suppliers

6-(Ferrocenyl)Hexanethiol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: FHT can be used as a SAM on gold substrates to act as an electron transport medium which can be potentially used in bio-electrochemical devices. FHT may also be used to functionalize graphene coated gold surfaces by forming gold-thiol linkages which can be used as electron transfer mediators.

Technology Process of 056-(FERROCENYL)HEXANETHIOL

There total 1 articles about 056-(FERROCENYL)HEXANETHIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ω-bromohexane ferrocene (136237-36-0) + thiourea (17356-08-0) → ω-ferrocenyl hexanethiol (134029-92-8)

Guidance literature:

With KOH; In ethanol; thiourea, C2H5OH, reflux, 18 h, then KOH, reflux, 2 h;

DOI:10.1002/anie.200500942

Reference yield:

ω-ferrocenyl hexanethiol (134029-92-8) + microcystin-LR → Fe(C5H5)(C5H4)(CH2)6S(C49H75N10O12) (551938-34-2)

Guidance literature:

With sodium carbonate; In ethanol; stirring at 60°C for 4 h; solid was removed by centrifugation, filtrate was evapd. to dryness, solid residue was dissolved in water, then centrifuged to removed solid residue, soln. was diluted with water, applied to HPLC; ED;

DOI:10.1039/b206384k

upstream raw materials:

ω-bromohexane ferrocene

thiourea

Downstream raw materials:

Fe(C₅H₅)(C₅H₄)(CH₂)6S(C₄₉H₇₅N₁₀O₁₂)