Technology Process of C33H46O2Si2
There total 8 articles about C33H46O2Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
methyl-triphenylphosphonium iodide;
With
lithium hexamethyldisilazane;
In
tetrahydrofuran;
at 0 ℃;
for 0.75h;
3-(tert-butyldimethylsilyloxy)-1-(2-((tert-butyldiphenylsilyloxy)methyl)phenyl)propan-1-one;
In
tetrahydrofuran;
at 23 ℃;
DOI:10.1002/ejoc.201402157
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 1H-imidazole / dichloromethane / 1.17 h / 0 - 20 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 - 20 °C
2.2: 2 h / 25 °C
3.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.75 h / 0 °C
3.2: 23 °C
With
1H-imidazole; oxalyl dichloride; dimethyl sulfoxide; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane;
2.1: |Swern Oxidation / 2.2: |Swern Oxidation;
DOI:10.1002/ejoc.201402157
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 - 20 °C
1.2: 2 h / 25 °C
2.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.75 h / 0 °C
2.2: 23 °C
With
oxalyl dichloride; dimethyl sulfoxide; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane;
1.1: |Swern Oxidation / 1.2: |Swern Oxidation;
DOI:10.1002/ejoc.201402157
