Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂

Base Information

• Chemical Name: Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂
• CAS No.: 205319-12-6
• Molecular Formula: C₃₈H₃₂Cl₂OP₂PtSi
• Molecular Weight: 860.691
• Mol file: 205319-12-6.mol

Synonyms:Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂

Chemical Property of Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂

There total 1 articles about Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

4,6-bis(diphenylphosphanyl)-10,10-dimethyl-10H-dibenzo[b,e][1,4]oxasilane (166330-11-6) → Si(CH3)2O(C6H3P(C6H5)2)2PtCl2 (205319-12-6)

Guidance literature:

With chloro-platinum(II) compound; In tetrahydrofuran; N2 atmosphere, stirring (room temp., overnight); removement of solvent (vacuum), washing (Et2O), drying (vacuum);

DOI:10.1002/(SICI)1099-0682(199802)1998:2<155::AID-EJIC155>3.0.CO;2-T

Reference yield: 88.0%

2-(diphenylphosphino)pyridine (37943-90-1) + Si(CH3)2O(C6H3P(C6H5)2)2PtCl2 (205319-12-6) + silver trifluoromethanesulfonate (2923-28-6) → sixantphos(2-(diphenylphosphino)pyridine)platinum(II)bistriflate

Guidance literature:

Si(CH₃)2O(C₆H₃P(C₆H₅)2)2PtCl₂; silver trifluoromethanesulfonate; In dichloromethane; for 3h; Schlenk technique; Glovebox; Darkness;

2-(diphenylphosphino)pyridine; In dichloromethane; Schlenk technique; Glovebox;

DOI:10.1039/c3dt32395a

Reference yield:

2-(diphenylphosphino)pyridine (37943-90-1) + Si(CH3)2O(C6H3P(C6H5)2)2PtCl2 (205319-12-6) → sixantphos(2-(diphenylphosphino)pyridine)hydridoplatinum(II)-bis-triflate

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 3 h / Schlenk technique; Glovebox; Darkness

1.2: Schlenk technique; Glovebox

2.1: diethylamine / dichloromethane / 40 °C / 3000.3 Torr / Inert atmosphere; High pressure

With diethylamine; In dichloromethane;

DOI:10.1039/c3dt32395a

upstream raw materials:

4,6-bis(diphenylphosphanyl)-10,10-dimethyl-10H-dibenzo[b,e][1,4]oxasilane