(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

Base Information

Chemical Name:(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone
CAS No.:161111-14-4
Molecular Formula:C₁₄H₁₅NO₄
Molecular Weight:261.277
Hs Code.:

(1S,6R)-1-<N-((Benzyloxy)carbonyl)amino>-3-oxabicyclo<4.1.0>-2-heptanone

Synonyms:(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

Chemical Property:

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Technology Process of (1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

There total 8 articles about (1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 161111-11-1
Di-tert-butyl (R)-2-(2-(benzyloxy)ethyl)cyclopropane-1,1-dicarboxylate

: 161111-14-4
(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

Guidance literature:: Multi-step reaction with 5 steps

1: 99 percent / H₂ / 10percent Pd/C / methanol

2: CF₃COOH / CH₂Cl₂ / Heating

3: TEA / acetone / 0.5 h

4: NaN₃ / acetone; H₂O / 0.5 h

5: Heating

With sodium azide; TEA; hydrogen; trifluoroacetic acid; palladium on activated charcoal; In methanol; dichloromethane; water; acetone;
DOI:10.1021/jo00097a040

Reference yield:

: 161111-10-0
Di-tert-butyl (4-(benzyloxy)-(S)-2-(tosyloxy)butyl)malonate

: 161111-14-4
(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / KHMDS / tetrahydrofuran / 1.) -78 to 0 deg C, 20 min, 2.) 0 deg C, 20 min

2: 99 percent / H₂ / 10percent Pd/C / methanol

3: CF₃COOH / CH₂Cl₂ / Heating

4: TEA / acetone / 0.5 h

5: NaN₃ / acetone; H₂O / 0.5 h

6: Heating

With sodium azide; TEA; hydrogen; potassium hexamethylsilazane; trifluoroacetic acid; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; water; acetone;
DOI:10.1021/jo00097a040

Reference yield:

: 1026365-09-2
C₁₀H₁₂O₆

: 161111-14-4
(1S,6R)-1--3-oxabicyclo<4.1.0>-2-heptanone

Guidance literature:: Multi-step reaction with 2 steps

1: NaN₃ / acetone; H₂O / 0.5 h

2: Heating

With sodium azide; In water; acetone;
DOI:10.1021/jo00097a040