Dimethylsilylbis(9-fluorenyl)zirconium dichloride

Base Information

• Chemical Name: Dimethylsilylbis(9-fluorenyl)zirconium dichloride
• CAS No.: 148799-45-5
• Molecular Formula: C₂₈H₂₂Cl₂SiZr
• Molecular Weight: 548.698
• Mol file: 148799-45-5.mol

Synonyms:Dimethylsilylbis(9-fluorenyl)zirconiumdichloride; Dimethylsilylenebisfluorenylzirconium dichloride

Chemical Property of Dimethylsilylbis(9-fluorenyl)zirconium dichloride

Chemical Property:

• PSA: 0.00000
• LogP: 7.69540

Purity/Quality:

98%min ^*data from raw suppliers

DIMETHYLSILYLBIS(9-FLUORENYL)ZIRCONIUM DICHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dimethylsilylbis(9-fluorenyl)zirconium dichloride

There total 2 articles about Dimethylsilylbis(9-fluorenyl)zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

zirconium chloride-tetrahydrofuran + di(9H-fluoren-9-yl)dimethylsilane (18769-00-1) → (dimethylsilanediylbis(9-fluorenyl))zirconium dichloride (148799-45-5)

Guidance literature:

di(9H-fluoren-9-yl)dimethylsilane; With n-butyllithium; In diethyl ether; hexane; for 24h; Schlenk technique;

zirconium chloride-tetrahydrofuran; In tetrahydrofuran; diethyl ether; at 20 ℃; for 24h; Schlenk technique; Glovebox;

Reference yield:

di(9H-fluoren-9-yl)dimethylsilane (18769-00-1) + zirconium(IV) chloride (10026-11-6) → (dimethylsilanediylbis(9-fluorenyl))zirconium dichloride (148799-45-5)

Guidance literature:

With n-butyllithium; In diethyl ether; byproducts: BuH; 2 equiv. butillithium added to soln. of ligand, stirred for 8 h at room temp., cooled to -78°C, 1 equiv. of ZrCl4 added, warmed to room temp., stirred for 6 h, evapd., residue suspnd. with CH2Cl2, filtered; washed (pentane, Et2O), recrystd. (-28°C, CH2Cl2);

DOI:10.1016/S1381-1169(02)00350-3

upstream raw materials:

di(9H-fluoren-9-yl)dimethylsilane

zirconium(IV) chloride