5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Base Information

Chemical Name:5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol
CAS No.:116490-87-0
Molecular Formula:C₄₃H₅₂O₁₄
Molecular Weight:792.877
Hs Code.:

Synonyms:5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Suppliers and Price of 5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

There total 1 articles about 5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116490-76-7
5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 116490-88-1
3,4,6-tri-O-acetyl-1,2-O-cyanoethylidene-α-D-glucopyranose

: 116490-87-0
5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Guidance literature:: With 4 A molecular sieve; mercury(II) cyanide; Yield given. Multistep reaction. Yields of byproduct given; 1.) benzene, 1 h, 0 deg C; 2.) nitromethane, 3 h, 50 deg C;
DOI:10.1016/0008-6215(88)84144-2

Reference yield: 86.7%

: 116490-87-0
5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

: 116490-89-2
1,2,3-Tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Guidance literature:: With sodium acetate; palladium dichloride; In water; acetic acid; for 48h; Ambient temperature;
DOI:10.1016/0008-6215(88)84144-2

Reference yield:

: 116490-87-0
5-O-Allyl1,2,3-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

: 116490-90-5
1,2,3-Tri-O-benzyl-5-O-diphenoxyphosphoryl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-ribitol

Guidance literature:: Multi-step reaction with 2 steps

1: 86.7 percent / sodium acetate, palladium chloride / acetic acid; H₂O / 48 h / Ambient temperature

2: 1.) 1,2,4-triazole, triethylamine, oxolane; 2.) 4-dimethylaminopyridine / 1.) 10 min at 10 deg C, 45 min at R_.T_.; 2.) pyridine, 1.5 h at 40 deg C

With tetrahydrofuran; 1,2,4-Triazole; dmap; sodium acetate; triethylamine; palladium dichloride; In water; acetic acid;
DOI:10.1016/0008-6215(88)84144-2