5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

Base Information

Chemical Name:5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol
CAS No.:116490-76-7
Molecular Formula:C₂₉H₃₄O₅
Molecular Weight:462.586
Hs Code.:

Synonyms:5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

Chemical Property:

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Technology Process of 5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

There total 6 articles about 5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 100-39-0
benzyl bromide

: 116490-75-6
5-O-allyl-2,3-di-O-benzyl-D-ribitol

: 111549-97-4
2,3,4-Tris-O-(phenylmethyl)-5-O-(prop-2-enyl)-D-ribitol

: 116490-76-7
5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

Guidance literature:: With sodium hydroxide; tetrabutylammomium bromide; In dichloromethane; for 16h; Heating;
DOI:10.1016/0008-6215(88)84144-2

Reference yield:

: 114488-50-5
β-5-O-allyl-1-O-methyl-2,3-O,O-isopropylidene-D-ribofuranoside

: 116490-76-7
5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / aqueous 50percent trifluoroacetic acide / H₂O; methanol / 8 h / Heating

2: 58 percent / pulverized potassium hydroxide / dimethylsulfoxide / Ambient temperature

3: 86 percent / 2M hydrochloric acid / dioxane / 8 h / Heating

4: 95 percent / sodium borohydride / ethanol / 2 h / Ambient temperature

5: 56 percent / aqueous 5percent sodium hydroxide, tetrabutylammonium bromide / CH₂Cl₂ / 16 h / Heating

With hydrogenchloride; potassium hydroxide; sodium hydroxide; sodium tetrahydroborate; tetrabutylammomium bromide; trifluoroacetic acid; In 1,4-dioxane; methanol; ethanol; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1016/0008-6215(88)84144-2

Reference yield:

: 4099-85-8,828937-29-7
((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methanol

: 116490-76-7
5-O-allyl-1,2,3-tri-O-benzyl-D-ribitol

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / aqueous 50percent sodium hydroxide, tetrabutylammonium bromide / H₂O / 6 h

2: 100 percent / aqueous 50percent trifluoroacetic acide / H₂O; methanol / 8 h / Heating

3: 58 percent / pulverized potassium hydroxide / dimethylsulfoxide / Ambient temperature

4: 86 percent / 2M hydrochloric acid / dioxane / 8 h / Heating

5: 95 percent / sodium borohydride / ethanol / 2 h / Ambient temperature

6: 56 percent / aqueous 5percent sodium hydroxide, tetrabutylammonium bromide / CH₂Cl₂ / 16 h / Heating

With hydrogenchloride; potassium hydroxide; sodium hydroxide; sodium tetrahydroborate; tetrabutylammomium bromide; trifluoroacetic acid; In 1,4-dioxane; methanol; ethanol; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1016/0008-6215(88)84144-2