9-Anthracenylmethyl methacrylate

Base Information

• Chemical Name: 9-Anthracenylmethyl methacrylate
• CAS No.: 31645-35-9
• Molecular Formula: C₁₉H₁₆O₂
• Molecular Weight: 276.335
• Hs Code.: 29161290
• European Community (EC) Number: 636-528-9
• DSSTox Substance ID: DTXSID70953610
• Nikkaji Number: J801.466C
• Wikidata: Q72443498
• Mol file: 31645-35-9.mol

Synonyms:31645-35-9;9-Anthracenylmethyl methacrylate;Anthracen-9-ylmethyl methacrylate;9-anthrylmethyl methacrylate;Anthracen-9-ylmethyl 2-methylprop-2-enoate;(ANTHRACEN-9-YL)METHYL 2-METHYLPROP-2-ENOATE;Methacrylic Acid 9-Anthrylmethyl Ester;9-anthrylmethylmethacrylate;9-Anthracenylmethylmethacrylate;(9-ANTHRYL) METHACRYLATE;SCHEMBL216321;Anthracen-9-ylmethylmethacrylate;9-Anthracene methyl methacrylate;9-Methacryloyloxymethylanthracene;DTXSID70953610;MJYSISMEPNOHEG-UHFFFAOYSA-N;AMY11195;MFCD00673247;AKOS015837648;9-Anthracenylmethyl methacrylate, 95%;CS-W012314;AS-61340;FT-0604853;T70759;A820940;2-methyl-2-propenoic acid 9-anthracenylmethyl ester;J-018503;51960-29-3

Chemical Property of 9-Anthracenylmethyl methacrylate

Chemical Property:

• Appearance/Colour: pale yellow crystals
• Vapor Pressure: 4.78E-08mmHg at 25°C
• Melting Point: 80-85 °C(lit.)
• Refractive Index: 1.647
• Boiling Point: 443 °C at 760 mmHg
• Flash Point: 286.4 °C
• PSA: 26.30000
• Density: 1.159 g/cm³
• LogP: 4.61230
• Storage Temp.: Keep Cold
• Solubility.: Acetone, Chloroform, Dichloromethane, hot Ethanol, Ethyl Acetate,
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 276.115029749
• Heavy Atom Count: 21
• Complexity: 378

Purity/Quality:

99% ^*data from raw suppliers

9-Anthryl Methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, F
• Hazard Codes: Xi,F
• Statements: 41
• Safety Statements: 25-26-36/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC1=C2C=CC=CC2=CC3=CC=CC=C31
• Description: 9-Anthrylmethyl Methacrylate is a fluorescent copolymer used as an optic fiber sensor for determination of Tetracycline.
• Uses: A fluorescent copolymer

Technology Process of 9-Anthracenylmethyl methacrylate

There total 3 articles about 9-Anthracenylmethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

9-hydroxymethylanthracene (1468-95-7) + Methacryloyl chloride (920-46-7,26937-45-1) → 9-anthrylmethyl methacrylate (31645-35-9)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/anie.202010429

Reference yield: 70.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 9-hydroxymethylanthracene (1468-95-7) → 9-anthrylmethyl methacrylate (31645-35-9)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In acetonitrile; for 24h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.6b01113

Reference yield:

→ 9-anthrylmethyl methacrylate (31645-35-9)

Guidance literature:

9-Chlormethylanthracen, 1.) CH2=C(CH3)-COOH, 80-85grad, 2.) CH3CN, (C2H5)3N;

upstream raw materials:

9-hydroxymethylanthracene

Methacryloyl chloride

poly(methacrylic acid)

Refernces

• 1、 Sakamoto, Hidefumi,Anase, Tomohiro,Osuga, Hideji,Kimura, Keiichi. "Complexation and fluorescence behavior of a copolymer bearing azacrown ether and anthracene moieties". . p. 569 - 573. Retrieved 2011.
• 2、 Bilgi, Mesut,Karaca Balta, Demet,Temel, Binnur Aydogan,Temel, Gokhan. "Single-Chain Folding Nanoparticles as Carbon Nanotube Catchers". . p. 2709 - 2714. Retrieved 2018.
• 3、 Yu, Xinjun,Cao, Xian,Chen, Xiaoping,Ayres, Neil,Zhang, Peng. "Triplet-triplet annihilation upconversion from rationally designed polymeric emitters with tunable inter-chromophore distances". . p. 588 - 591. Retrieved 2015.