methyl 7-<oxy>naphthalene-2-carboxylate

Base Information

Chemical Name:methyl 7-<oxy>naphthalene-2-carboxylate
CAS No.:145970-34-9
Molecular Formula:C₁₈H₂₄O₃Si
Molecular Weight:316.472
Hs Code.:

methyl 7-<<dimethyl(1,1-dimethylethyl)silyl>oxy>naphthalene-2-carboxylate

Synonyms:methyl 7-<oxy>naphthalene-2-carboxylate

Suppliers and Price of methyl 7-<oxy>naphthalene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 7-<oxy>naphthalene-2-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 7-<oxy>naphthalene-2-carboxylate

There total 1 articles about methyl 7-<oxy>naphthalene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 187962-05-6
3-[7-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane

: 145970-34-9
methyl 7-<oxy>naphthalene-2-carboxylate

: 565-80-0
2,4-dimethylpentan-3-one

Guidance literature:: With tetrabutyl ammonium fluoride; In dimethyl sulfoxide; at 25 ℃; Quantum yield;
DOI:10.1016/S0040-4039(96)02312-X

Reference yield:

: 145970-34-9
methyl 7-<oxy>naphthalene-2-carboxylate

: 145970-18-9
3-[7-(1-Hydroxy-nonyl)-naphthalen-2-ylmethylsulfanyl]-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: 95 percent / DIBAL / CH₂Cl₂ / 0.25 h / -78 °C

2: 84 percent / MnO₂ / CH₂Cl₂ / 18 h / Ambient temperature

3: 84 percent / tetrahydrofuran / 0.17 h / -25 °C

4: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

5: 96 percent / K₂CO₃, methanol / tetrahydrofuran / 1 h

6: 90 percent / pyridine / CH₂Cl₂ / 0.5 h / 0 °C

7: 98 percent / Et₃N, Pd(OAc)2, 1,3-bis(diphenylphosphino)propane / dimethylsulfoxide / 1 h / 75 °C

8: 100 percent / DIBAL / CH₂Cl₂ / 0.33 h / -78 °C

9: 91 percent / CBr₄, Ph₃P / CH₂Cl₂ / 1 h

10: 95 percent / K₂CO₃ / dimethylformamide / 0.5 h

11: TBAF / tetrahydrofuran / 48 h / Ambient temperature

With pyridine; 2,6-dimethylpyridine; methanol; manganese(IV) oxide; palladium diacetate; carbon tetrabromide; 1,3-bis-(diphenylphosphino)propane; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; potassium carbonate; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1021/jm00074a012

Reference yield:

: 145970-34-9
methyl 7-<oxy>naphthalene-2-carboxylate

: 145970-20-3
methyl 2-<<<7-(1-hydroxynonyl)naphthalen-2-yl>methyl>sulfinyl>benzoate

Guidance literature:: Multi-step reaction with 12 steps

1: 95 percent / DIBAL / CH₂Cl₂ / 0.25 h / -78 °C

2: 84 percent / MnO₂ / CH₂Cl₂ / 18 h / Ambient temperature

3: 84 percent / tetrahydrofuran / 0.17 h / -25 °C

4: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

5: 96 percent / K₂CO₃, methanol / tetrahydrofuran / 1 h

6: 90 percent / pyridine / CH₂Cl₂ / 0.5 h / 0 °C

7: 98 percent / Et₃N, Pd(OAc)2, 1,3-bis(diphenylphosphino)propane / dimethylsulfoxide / 1 h / 75 °C

8: 100 percent / DIBAL / CH₂Cl₂ / 0.33 h / -78 °C

9: 91 percent / CBr₄, Ph₃P / CH₂Cl₂ / 1 h

10: 95 percent / K₂CO₃ / dimethylformamide / 0.5 h

11: TBAF / tetrahydrofuran / 48 h / Ambient temperature

12: 72 percent / 80percent MCPBA / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine; 2,6-dimethylpyridine; methanol; manganese(IV) oxide; palladium diacetate; carbon tetrabromide; 1,3-bis-(diphenylphosphino)propane; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1021/jm00074a012