cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]

Base Information

• Chemical Name: cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]
• CAS No.: 865186-98-7
• Molecular Formula: C₃₇H₄₀N₂P₂Pt₂
• Molecular Weight: 964.846
• Mol file: 865186-98-7.mol

Synonyms:cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]

Chemical Property of cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]

There total 1 articles about cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

PHTHALAZINE (253-52-1) + cis,cis-[Me2Pt(μ-SMe2)(μ-bis(diphenylphosphino)methane)PtMe2] (380613-02-5) → cis-[Me2Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe2] (865186-98-7)

Guidance literature:

In acetone; to soln. Pt complex in acetone soln. phthalazine in acetone was added atroom temp. and stirred for 1 h; solvent was removed in vacuo, residue was triturated with ether, ppt. was dried in vacuo; elem. anal.;

DOI:10.1021/ic0511064

Reference yield:

cis-[Me2Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe2] (865186-98-7) + methyl iodide (74-88-4) → [(PtMe3(μ-I))2(μ-bis(diphenylphosphino)methane)] (133892-26-9)

Guidance literature:

In benzene; 5-35°C; Kinetics;

DOI:10.1021/ic0511064

Reference yield:

cis-[Me2Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe2] (865186-98-7) + bis-diphenylphosphinomethane (2071-20-7) → [Me2Pt(μ-bis(diphenylphosphino)methane)2PtMe2]

Guidance literature:

In benzene; soln. of P ligand in C6H6 was added to soln. of Pt complex in C6H6; stirred; UV monitoring; Kinetics;

DOI:10.1016/j.jorganchem.2007.01.007

upstream raw materials:

PHTHALAZINE

cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]

Downstream raw materials:

[(PtMe3(μ-I))2(μ-bis(diphenylphosphino)methane)]