(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

Base Information

Chemical Name:(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol
CAS No.:104619-26-3
Molecular Formula:C₂₄H₃₀N₂O₅
Molecular Weight:426.513
Hs Code.:

Synonyms:(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

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Chemical Property of (+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

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Technology Process of (+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

There total 1 articles about (+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104619-22-9
(-)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexanetetrol

: 74-88-4
methyl iodide

: 104619-26-3
(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

: 104619-25-2
(-)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-2-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexanetetrol

: 104619-24-1
(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1,2-di-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexanetetrol

Guidance literature:: With sodium hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) glyme, 20 deg C, 10 min; 2.) 20 deg C, 10 min;
DOI:10.1002/jlac.198619861201

Reference yield: 88.0%

: 108-24-7
acetic anhydride

: 104619-26-3
(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

: 104619-27-4
(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexanetetrol 2-Acetate

Guidance literature:: With pyridine; dmap; at 20 ℃; for 24h;
DOI:10.1002/jlac.198619861201

Reference yield:

: 104619-26-3
(+)-(1R)-(1α,2α,3β,4α,5β,6β)-4-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexane-tetrol

: 79951-95-4
(-)-(1R)-(1α,2α,3β,4α,5β,6β)-3-Ammonio-1-O-methyl-6-(methylammonio)-1,2,4,5-cyclohexanetetrol Sulfate

Guidance literature:: Multi-step reaction with 3 steps

1: H₂SO₄, H₂ / Pd/C (10percent) / methanol / 24 h / 20 °C / 735.5 Torr

2: 93 percent / pyridine, DMAP / 24 h / 20 °C

3: 96 percent / Ba(OH)2, H₂SO₄ / H₂O / 6 h / Heating

With pyridine; dmap; barium dihydroxide; sulfuric acid; hydrogen; palladium on activated charcoal; In methanol; water;
DOI:10.1002/jlac.198619861201