4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

Base Information

Chemical Name:4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane
CAS No.:638164-10-0
Molecular Formula:C₁₈H₂₉BO₇
Molecular Weight:368.235
Hs Code.:

Synonyms:4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

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Chemical Property of 4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

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Technology Process of 4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

There total 2 articles about 4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 638164-07-5
2-iodo-3,4,5-trimethoxy-1-methoxymethoxymethyl-benzene

: 638164-10-0
4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

Guidance literature:: With triethylamine; CyJohnPhos; palladium diacetate; In 1,4-dioxane; at 80 ℃; for 0.5h;
DOI:10.1055/s-2003-42039

Reference yield:

: 64490-45-5
2-iodo-3,4,5-trimethoxybenzyl alcohol

: 638164-10-0
4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / iPr₂NEt / CH₂Cl₂ / 15 h / 0 - 25 °C

2: 79 percent / Et₃N; 2-(dicyclohexylphosphino)biphenyl / Pd(OAc)2 / dioxane / 0.5 h / 80 °C

With triethylamine; N-ethyl-N,N-diisopropylamine; CyJohnPhos; palladium diacetate; In 1,4-dioxane; dichloromethane;
DOI:10.1055/s-2003-42039

Reference yield: 74.0%

: 52199-45-8
2-(2'-iodo-4',5'-methylenedioxyphenyl)ethanol

: 638164-10-0
4,4,5,5-tetramethyl-2-(2,3,4-trimethoxy-6-methoxymethoxymethyl-phenyl)-[1,3,2]dioxaborolane

: C₂₁H₂₆O₈

Guidance literature:: With barium dihydroxide; DavePhos; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In 1,4-dioxane; water; at 110 ℃; for 1h;
DOI:10.1002/chem.200601764