3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

Base Information

Chemical Name:3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine
CAS No.:1026490-94-7
Molecular Formula:C₂₃H₂₇NO₄S
Molecular Weight:413.538
Hs Code.:

3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2<i>H</i>-1,3-dioxa-cyclopropa[<i>a</i>]naphthalene-6-sulfonyl)-piperidine

Synonyms:3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

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Chemical Property of 3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

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Technology Process of 3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

There total 3 articles about 3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1026916-01-7
3-benzyl-1-(2,2-dimethyl-2H-chromene-6-sulfonyl)-piperidine

: 1026490-94-7
3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

Guidance literature:: With sodium hypochlorite; 4-Phenylpyridine 1-oxide; Jacobsen's catalyst; In water; at 0 ℃; for 18h; pH=11.3;
DOI:10.1021/jm990196h

Reference yield:

: 13603-25-3
3-benzylpiperidine

: 1026490-94-7
3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 2 h / 20 °C

2: sodium hypochlorite; (S,S)-(+)-Jacobsen's catalyst; 4-phenylpyridine-N-oxide / H₂O / 18 h / 0 °C / pH 11.3

With sodium hypochlorite; 4-Phenylpyridine 1-oxide; Jacobsen's catalyst; In dichloromethane; water; 1: Acylation / 2: Epoxidation;
DOI:10.1021/jm990196h

Reference yield:

: 185316-64-7
2,2-dimethyl-2H-1-benzopyran-6-sulfonyl chloride

: 1026490-94-7
3-benzyl-1-(2,2-dimethyl-1a,7b-dihydro-2H-1,3-dioxa-cyclopropa[a]naphthalene-6-sulfonyl)-piperidine

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 2 h / 20 °C

2: sodium hypochlorite; (S,S)-(+)-Jacobsen's catalyst; 4-phenylpyridine-N-oxide / H₂O / 18 h / 0 °C / pH 11.3

With sodium hypochlorite; 4-Phenylpyridine 1-oxide; Jacobsen's catalyst; In dichloromethane; water; 1: Acylation / 2: Epoxidation;
DOI:10.1021/jm990196h