ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

Base Information

Chemical Name:ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate
CAS No.:951386-31-5
Molecular Formula:C₂₉H₄₀O₃Si
Molecular Weight:464.72
Hs Code.:

Synonyms:ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

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Chemical Property of ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

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Technology Process of ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

There total 3 articles about ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 951386-30-4
4-(tert-butyldiphenylsilyloxy)-2-isopropylidenecyclohexanol

: 78-39-7
Triethyl orthoacetate

: 951386-31-5
ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

Guidance literature:: With propionic acid; at 138 ℃; for 8h;
DOI:10.1021/jo071156l

Reference yield:

: 951386-29-1
2-isopropylidene-4-(tert-butyldiphenylsilyloxy)cyclohexanone

: 951386-31-5
ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / NaBH₄; CeCl₃ / methanol / 0.5 h

2: 85 percent / propionic acid / 8 h / 138 °C

With sodium tetrahydroborate; cerium(III) chloride; propionic acid; In methanol;
DOI:10.1021/jo071156l

Reference yield:

: 130745-59-4
4-<(tert-Butyldiphenylsilyl)oxy>cyclohexanone

: 951386-31-5
ethyl 3-[5-(tert-butyldiphenylsilyloxy)cyclohex-1-enyl]-3-methylbutyrate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium; HN(TMS)2; ZnCl₂ / tetrahydrofuran / 0.5 h / -78 °C

1.2: 75 percent / PTSA / benzene / 2 h / Heating

2.1: 94 percent / NaBH₄; CeCl₃ / methanol / 0.5 h

3.1: 85 percent / propionic acid / 8 h / 138 °C

With sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; propionic acid; 1,1,1,3,3,3-hexamethyl-disilazane; zinc(II) chloride; In tetrahydrofuran; methanol;
DOI:10.1021/jo071156l