tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

Base Information

Chemical Name:tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane
CAS No.:1234693-78-7
Molecular Formula:C₂₄H₄₂O₃Si
Molecular Weight:406.681
Hs Code.:

Synonyms:tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

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Chemical Property of tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

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Technology Process of tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

There total 2 articles about tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1181635-81-3
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-3,6-dimethyloct-1-en-4-ol

: 2746-25-0
p-Methoxybenzyl bromide

: 1234693-78-7
tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

Guidance literature:: (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-3,6-dimethyloct-1-en-4-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 0.5h; Inert atmosphere;

p-Methoxybenzyl bromide; In tetrahydrofuran; mineral oil; for 2h; Inert atmosphere; Reflux;
DOI:10.1021/ol1011423

Reference yield: 84.0%

: 1181635-81-3
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-3,6-dimethyloct-1-en-4-ol

: 824-94-2
p-methoxybenzyl chloride

: 1234693-78-7
tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

Guidance literature:: (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-3,6-dimethyloct-1-en-4-ol; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.5h;

p-methoxybenzyl chloride; In N,N-dimethyl-formamide; mineral oil; at 0 - 20 ℃;
DOI:10.1021/ol101105v

Reference yield: 83.0%

: 1234693-78-7
tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

: 1234707-92-6
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

Guidance literature:: tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane; With borane-THF; In tetrahydrofuran; at 0 ℃; for 1.5h; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 1h;
DOI:10.1021/ol1011423