(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

Base Information

Chemical Name:(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol
CAS No.:1234707-92-6
Molecular Formula:C₂₄H₄₄O₄Si
Molecular Weight:424.696
Hs Code.:

Synonyms:(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

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Chemical Property of (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

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Technology Process of (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

There total 2 articles about (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1234693-78-7
tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane

: 1234707-92-6
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

Guidance literature:: tert-butyl((2S,3S,5R,6S)-5-(4-methoxybenzyloxy)-3,6-dimethyloct-7-en-2-yloxy)dimethylsilane; With borane-THF; In tetrahydrofuran; at 0 ℃; for 1.5h; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 1h;
DOI:10.1021/ol1011423

Reference yield:

: C₃₂H₅₇BO₃Si

: 1234707-92-6
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

Guidance literature:: With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; for 1h; Reflux;
DOI:10.1021/ol101105v

Reference yield: 95.0%

: 1234707-92-6
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol

: 1234707-93-7
(3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctanal

Guidance literature:: (3S,4R,6S,7S)-7-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-3,6-dimethyloctan-1-ol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 0.5h; Inert atmosphere;

With triethylamine; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol1011423