Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Base Information

Chemical Name:Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester
CAS No.:82130-97-0
Molecular Formula:C₁₈H₂₇BrO₆S
Molecular Weight:451.379
Hs Code.:

Synonyms:Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Suppliers and Price of Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

There total 9 articles about Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-39-0
benzyl bromide

: 82130-97-0
Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / Ag₂O / ethyl acetate

2: 68 percent / diisobutylaluminium hydride / 1.33 h / -75 - -60 °C

3: 42 percent / p-toluenesulphonic acid

With diisobutylaluminium hydride; silver(l) oxide; toluene-4-sulfonic acid; In ethyl acetate;
DOI:10.1016/S0040-4039(00)86913-0

Reference yield:

: 82130-86-7
2,5-di-O-tosyl-D-ribono-1,4-lactone

: 82130-97-0
Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: LiBr / acetone

2: 53 percent / NaI, TFA / acetone

3: 90 percent / Ag₂O / ethyl acetate

4: 68 percent / diisobutylaluminium hydride / 1.33 h / -75 - -60 °C

5: 42 percent / p-toluenesulphonic acid

With diisobutylaluminium hydride; trifluoroacetic acid; sodium iodide; lithium bromide; silver(l) oxide; toluene-4-sulfonic acid; In ethyl acetate; acetone;
DOI:10.1016/S0040-4039(00)86913-0

Reference yield:

: 78139-03-4
(4S,5S)-5-(bromomethyl)-4-hydroxydihydrofuran-2(3H)-one

: 82130-97-0
Methanesulfonic acid (1S,2S)-2-benzyloxy-1-bromomethyl-3-(5,5-dimethyl-[1,3]dioxan-2-yl)-propyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / Ag₂O / ethyl acetate

2: 68 percent / diisobutylaluminium hydride / 1.33 h / -75 - -60 °C

3: 42 percent / p-toluenesulphonic acid

With diisobutylaluminium hydride; silver(l) oxide; toluene-4-sulfonic acid; In ethyl acetate;
DOI:10.1016/S0040-4039(00)86913-0