ethyl 1-ethynylcyclohexyl carbonate

Base Information

• Chemical Name: ethyl 1-ethynylcyclohexyl carbonate
• CAS No.: 95174-35-9
• Molecular Formula: C₁₁H₁₆O₃
• Molecular Weight: 196.246
• Mol file: 95174-35-9.mol

Synonyms:ethyl 1-ethynylcyclohexyl carbonate

Chemical Property of ethyl 1-ethynylcyclohexyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 1-ethynylcyclohexyl carbonate

There total 2 articles about ethyl 1-ethynylcyclohexyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroformic acid ethyl ester (541-41-3) + 1-Ethynylcyclohexan-1-ol (78-27-3) → ethyl 1-ethynylcyclohexyl carbonate (95174-35-9)

Guidance literature:

1-Ethynylcyclohexan-1-ol; With sodium hydride; In N,N-dimethyl-formamide; for 0.166667h; Cooling with ice;

chloroformic acid ethyl ester; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.3762/bjoc.12.197

Reference yield:

→ ethyl 1-ethynylcyclohexyl carbonate (95174-35-9)

Guidance literature:

Na-<1-ethinyl-cyclohexanolat> in Bzl., Chlorameisensaeureethylester;

Reference yield: 95.0%

ethyl 1-ethynylcyclohexyl carbonate (95174-35-9) + diazomethyl-trimethyl-silane (18107-18-1) → C12H18O3 (1446452-02-3)

Guidance literature:

With styrene; chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II); In methanol; diethyl ether; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201203796

upstream raw materials:

chloroformic acid ethyl ester

1-Ethynylcyclohexan-1-ol

Downstream raw materials:

C₁₂H₁₈O₃

C₁₅H₂₆O₃Si

C₁₅H₂₆O₃Si

<2-Methoxy-ethyl>-cyclohexyl-keton