η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate

Base Information

• Chemical Name: η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate
• CAS No.: 221639-07-2
• Molecular Formula: C₁₉H₂₀FeNSe*F₆P
• Molecular Weight: 542.146
• Mol file: 221639-07-2.mol

Synonyms:η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate

Chemical Property of η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate

There total 1 articles about η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(η6-chlorobenzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate + 4,4′(N,N′-dimethylaniline)diselenide (52673-28-6) → η(6)-[4-(dimethylamino)phenylseleno]benzene-η(5)-(cyclopentadienyl)iron hexafluorophosphate (221639-07-2)

Guidance literature:

With hydrogenchloride; sodium tetrahydroborate; sodium hydrogencarbonate; In tetrahydrofuran; ethanol; acetone; Ph2Se2 soln. (THF) dropwise addn. to NaBH4 soln. (EtOH), Fe-compd. suspn. (Me2CO) addn., stirring (room temp., overnight), evapn., 0.1 M HCl / NH4PF6 addn., NaHCO3 addn.; extg. (CH2Cl2), drying, evapn., chromy. (alumina, ether, Me2CO), crystn.(Me2CO / ether); elem. anal.;

DOI:10.1021/om980948q

upstream raw materials:

4,4′(N,N′-dimethylaniline)diselenide