(R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE

Base Information

• Chemical Name: (R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE
• CAS No.: 121680-77-1
• Molecular Formula: C8H3 F5 O
• Molecular Weight: 210.1
• Mol file: 121680-77-1.mol

Synonyms:Oxirane,(pentafluorophenyl)-, (R)-; (R)-(Pentafluorophenyl)oxirane

Chemical Property of (R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE

Chemical Property:

• PSA: 12.53000
• LogP: 2.45340

Purity/Quality:

98%min ^*data from raw suppliers

(R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE

There total 2 articles about (R)-(+)-2,3,4,5,6-PENTAFLUOROSTYRENE OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,5,6-pentafluorostyrene (653-34-9,26838-55-1) → (R)-(+)-2,3,4,5,6-pentafluorostyrene oxide (121680-77-1) + (S)-2-Pentafluorophenyl-oxirane (220276-46-0)

Guidance literature:

With iodosylbenzene; chiral iron "twin coronet" porphyrin; In dichloromethane; at 0 ℃; for 3h; Yield given. Yields of byproduct given;

DOI:10.1246/cl.1991.1933

Reference yield:

1,3-dinitro-5-vinylbenzene (72918-18-4) → (R)-(+)-2,3,4,5,6-pentafluorostyrene oxide (121680-77-1) + (S)-2-Pentafluorophenyl-oxirane (220276-46-0)

Guidance literature:

With iodosylbenzene; FeCl<(S)-Bitet(OMe)2>4TPP-eclipsed; In dichloromethane; for 3h; Title compound not separated from byproducts;

DOI:10.1246/bcsj.66.158

Reference yield: 94.0%

trimethylaluminum (75-24-1) + (R)-(+)-2,3,4,5,6-pentafluorostyrene oxide (121680-77-1) → (+)-2-(pentafluorophenyl)-1-propanol (82875-60-3)

Guidance literature:

In hexane; dichloromethane; for 2h;

DOI:10.1016/S0040-4039(00)74487-X

upstream raw materials:

2,3,4,5,6-pentafluorostyrene

1,3-dinitro-5-vinylbenzene

Downstream raw materials:

(+)-2-(pentafluorophenyl)-1-propanol

(R)-1-(pentafluorophenyl)-2-(phenylthio)ethanol

(S)-2-(pentafluorophenyl)-2-(phenylthio)ethanol

(R)-(-)-2-bromo-1-(pentafluorophenyl)-ethanol