82875-60-3Relevant academic research and scientific papers
An exceptional hydroboration of substituted fluoroolefins providing tertiary alcohols
Ramachandran, P. Veeraraghavan,Jennings, Michael P.
, p. 3789 - 3790 (2007/10/03)
Figure presented A rare hydroboration-oxidation providing 3°-alcohols has been achieved in the case of 1,1,2-perfluoroalkyl(aryl)ethylenes. The hydroboration of substituted perfluoroalkyl(aryl)ethylenes with dichloroborane reveals that the regioselectivit
Pentafluorophenyl derivatives, methods of production thereof, and method of optical resolution of chiral carboxylic acids
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, (2008/06/13)
Pentafluorophenyl derivatives are expressed by the formula (I): STR1 where X represents an alkyl group having from 1 to 4 carbon atoms or a halogen atom; Y represents any group of --CH2 OH, --COOH, --COCl, --CON1 R2, or --
Asymmetric synthesis of α-methyl carboxylic acid derivatives stereochemistry in acidic ring opening of epoxides
Fukumasa,Furuhashi,Umezawa,Takahashi,Hirai
, p. 1059 - 1062 (2007/10/02)
Optically active α-methyl carboxylic acid derivatives were prepared via reaction of microbially produced epoxides with trimethylaluminum. Stereochemistry of the ring opening reaction was discussed through an MO calculation.
