[η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

Base Information

Chemical Name:[η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)
CAS No.:569370-85-0
Molecular Formula:C₁₈H₁₅CrNO₅
Molecular Weight:377.317
Hs Code.:

Synonyms:[η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

Suppliers and Price of [η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

There total 1 articles about [η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: (η6-benzylammonium)tricarbonylchromium(0) trifluoroacetate

: 501-53-1,94274-21-2
benzyl chloroformate

: 569370-85-0
[η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

Guidance literature:: With potassium hydrogencarbonate; In diethyl ether; water; (N2); stirring a mixt. of chromium complex with satd. aq. KHCO3 in Et2O at room temp. for 10 min, addn. of chloroformate, stirring for 0.5 h; sepn., extn. aq. layer with Et2O, washing org phase with brine, drying (Na2SO4), evapn., flash chromy. (SiO2, CH2Cl2/petroleum ether 8:2); elem.anal.;
DOI:10.1039/b211222c

Reference yield:

: 569370-85-0
[η6-N-(benzyloxycarbonyl)benzylamine]tricarbonylchromium(0)

: 2Li⁽¹⁺⁾*(C₆H₅CHCH₃NCHC₆H₅)2^(2-)=Li₂(C₆H₅CHCH₃NCHC₆H₅)2

: 74-88-4
methyl iodide

: 569370-87-2,569370-88-3
(+/-)-[η6-N-(benzyloxycarbonyl)-1-phenylethylamine]tricarbonylchromium(0)

Guidance literature:: With n-butyllithium; lithium chloride; In tetrahydrofuran; hexane; (N2); addn. of a soln. of LiCl in THF to a soln. of lithium compd. in hexanes/THF at -78°C, addn. of a soln. of BuLi in hexanes to a soln. of chromium complex in THF at -78°C, combining at -40°C for 2.5 h, addn. of MeI; addn. of methanol, warming to room temp., evapn., flash chromy. (SiO2, toluene/Et2O 50:1); not isolated;
DOI:10.1039/b211222c