{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

Base Information

Chemical Name:{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane
CAS No.:204004-81-9
Molecular Formula:C₂₂H₃₉N₃O₂Si
Molecular Weight:405.656
Hs Code.:

Synonyms:{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

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Chemical Property of {(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

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Technology Process of {(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

There total 5 articles about {(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 63072-78-6,50999-04-7
sorbyl bromide

: 204004-80-8
(1R,6S)-2-(2-Azido-ethyl)-6-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclohex-2-enol

: 204004-81-9
{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

Guidance literature:: With sodium hydride; In tetrahydrofuran; Ambient temperature; 1.) 0 deg C, 20 min, 2.) r.t., 14 h;
DOI:10.1055/s-1998-4529

Reference yield:

: 6926-44-9
phenethyl azide

: 204004-81-9
{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

Guidance literature:: Multi-step reaction with 4 steps

1: Escherichia coli JM₁₀₉(pDTG₆₀₁)

2: 72 percent / potassium azodicarboxylate, HOAc / methanol / 14 h / Ambient temperature

3: 99 percent / imidazole / dimethylformamide / 13 h / 0 °C

4: 58 percent / NaH / tetrahydrofuran / Ambient temperature; 1.) 0 deg C, 20 min, 2.) r.t., 14 h

With 1H-imidazole; Escherichia coli JM₁₀₉(pDTG₆₀₁); potassium diazodicarboxylate; sodium hydride; acetic acid; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1055/s-1998-4529

Reference yield:

: 103-63-9
1-phenyl-2-bromoethane

: 204004-81-9
{(1S,2R)-3-(2-Azido-ethyl)-2-[((2E,4E)-hexa-2,4-dienyl)oxy]-cyclohex-3-enyloxy}-dimethyl-(1,1,2-trimethyl-propyl)-silane

Guidance literature:: Multi-step reaction with 5 steps

1: NaN₃ / dimethylformamide

2: Escherichia coli JM₁₀₉(pDTG₆₀₁)

3: 72 percent / potassium azodicarboxylate, HOAc / methanol / 14 h / Ambient temperature

4: 99 percent / imidazole / dimethylformamide / 13 h / 0 °C

5: 58 percent / NaH / tetrahydrofuran / Ambient temperature; 1.) 0 deg C, 20 min, 2.) r.t., 14 h

With 1H-imidazole; sodium azide; Escherichia coli JM₁₀₉(pDTG₆₀₁); potassium diazodicarboxylate; sodium hydride; acetic acid; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1055/s-1998-4529