C₁₇H₂₆O₄Si

Base Information

• Chemical Name: C₁₇H₂₆O₄Si
• CAS No.: 1265278-86-1
• Molecular Formula: C₁₇H₂₆O₄Si
• Molecular Weight: 322.477
• Mol file: 1265278-86-1.mol

Synonyms:C₁₇H₂₆O₄Si

Chemical Property of C₁₇H₂₆O₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₁₇H₂₆O₄Si

There total 1 articles about C₁₇H₂₆O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

trimethyl phosphonoacetate (5927-18-4) + 3-[(tert-butyldimethylsilyl)oxy]-2-methoxybenzaldehyde → C17H26O4Si (1265278-86-1)

Guidance literature:

trimethyl phosphonoacetate; With lithium bromide; In tetrahydrofuran; at 23 ℃; for 0.25h; Inert atmosphere;

With triethylamine; In tetrahydrofuran; at 23 ℃; for 0.25h; Inert atmosphere;

3-[(tert-butyldimethylsilyl)oxy]-2-methoxybenzaldehyde; In tetrahydrofuran; at 23 ℃; for 5h; Inert atmosphere;

DOI:10.1002/ejoc.201001281

Reference yield: 90.0%

C17H26O4Si (1265278-86-1) → C17H28O4Si (1265278-87-2)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; at 23 ℃; for 0.5h;

DOI:10.1002/ejoc.201001281

Reference yield:

C17H26O4Si (1265278-86-1) → C19H32O3Si (1265278-89-4)

Guidance literature:

Multi-step reaction with 3 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 0.5 h / 23 °C

2: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / Inert atmosphere

3: tetrahydrofuran / 2 h / -78 - 23 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrogen; diisobutylaluminium hydride; In tetrahydrofuran; methanol; dichloromethane; toluene;

DOI:10.1002/ejoc.201001281

upstream raw materials:

trimethyl phosphonoacetate

Downstream raw materials:

C₁₉H₃₂O₃Si

C₁₃H₁₈O₃

C₁₇H₂₈O₄Si

C₁₆H₂₆O₃Si