3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Base Information

Chemical Name:3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole
CAS No.:1340541-06-1
Molecular Formula:C₅₉H₄₉N₅Zn
Molecular Weight:893.462
Hs Code.:

Synonyms:3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Suppliers and Price of 3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

There total 7 articles about 3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 3-(5,10,15-tris(4-methylphenyl)porphyrin-20-yl)-9-hexyl-carbazole

: 1340541-06-1
3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Guidance literature:: With zinc diacetate; In methanol; chloroform; at 70 ℃; for 0.5h;
DOI:10.1016/j.tet.2011.08.096

Reference yield:

: 864550-95-8
2-bromo-9-hexylcarbazole

: 1340541-06-1
3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexanes / 2.5 h / -78 °C

1.2: 18 h / -78 - 20 °C

2.1: potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 18 h / 80 °C / Inert atmosphere

3.1: zinc diacetate / methanol; chloroform / 0.5 h / 70 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; zinc diacetate; In tetrahydrofuran; methanol; hexanes; chloroform; 2.1: Suzuki coupling;
DOI:10.1016/j.tet.2011.08.096

Reference yield:

: 3652-90-2
2-bromo-9H-carbazole

: 1340541-06-1
3-(5,10,15-tris(4-methylphenyl)porphyrinato(zinc)(II)-20-yl)-9-hexyl-carbazole

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium tert-butylate / N,N-dimethyl-formamide / 20 °C

1.2: 130 °C

2.1: n-butyllithium / tetrahydrofuran; hexanes / 2.5 h / -78 °C

2.2: 18 h / -78 - 20 °C

3.1: potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 18 h / 80 °C / Inert atmosphere

4.1: zinc diacetate / methanol; chloroform / 0.5 h / 70 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; potassium tert-butylate; zinc diacetate; In tetrahydrofuran; methanol; hexanes; chloroform; N,N-dimethyl-formamide; 3.1: Suzuki coupling;
DOI:10.1016/j.tet.2011.08.096