RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine)

Base Information

• Chemical Name: RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine)
• CAS No.: 199661-81-9
• Molecular Formula: C₄₃H₆₇ClNOP₂RhSi
• Molecular Weight: 842.403
• Mol file: 199661-81-9.mol

Synonyms:RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine)

Chemical Property of RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine)

There total 1 articles about RhCl(P(iPr)3)2(H)(C*C-C*C-CPh₂OSiMe₃)(pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyridine (110-86-1) + RhCl(P(iPr)3)2(HC*C-C*C-CPh2OSiMe3) (199661-78-4) → RhCl(P(iPr)3)2(H)(C*C-C*C-CPh2OSiMe3)(pyridine) (199661-81-9)

Guidance literature:

In benzene; elem. anal.;

DOI:10.1021/om970734t

Reference yield: 60.0%

RhCl(P(iPr)3)2(H)(C*C-C*C-CPh2OSiMe3)(pyridine) (199661-81-9) → trans-[RhCl(=C=C=C=C=CPh2)(P(i)Pr3)2]

Guidance literature:

With trifluoromethylsulfonic anhydride; triethylamine; In toluene; addn. of Tf2O to soln. of Rh-complex at -78°C, warming to room temp., addn. of excess of NEt3; NMR spectroscopy;

DOI:10.1021/om970734t

Reference yield: 49.0%

RhCl(P(iPr)3)2(H)(C*C-C*C-CPh2OSiMe3)(pyridine) (199661-81-9) + trifluorormethanesulfonic acid (1493-13-6) → RhCl(P(CH(CH3)2)3)2(CCHC(O)CHC(C6H5)2)

Guidance literature:

With H₂O; In tetrahydrofuran; water; under Ar; soln. of Rh complex in THF treated at -78°C with H2O and then with CF3SO3H; slowly warmed to room temp. under stirring; concd. in vac.; chromd. (acidic Al2O3, chilled toluene (-50°C)); orange fraction collected; solvent removed in vac.; pentane added; stored for 6 h; ppt. sepd.; washed with pentane (-20°C); dried in vac.; elem. anal.;

DOI:10.1039/c1nj20392d

upstream raw materials:

pyridine

RhCl(P(iPr)3)2(HC*C-C*C-CPh₂OSiMe₃)