Technology Process of Hg(o-C6H4-2-CH(O2C2H4))2
There total 1 articles about Hg(o-C6H4-2-CH(O2C2H4))2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
Mg; I2;
In
tetrahydrofuran;
Mg was stirred in THF, I2 was added under N2, ligand in THF was added, refluxed for 1 h, cooled to 0°C, HgBr2 in THF was added for 1 h, warmed to room temp., stirred for 18 h; NH4Cl was added, organic layer was sepd., aq. layer was extd. with toluene, dried over MgSO4, filtered, solvent was removed under reduced pressure, recrystd. from hot EtOH; elem. anal.;
DOI:10.1021/ic010881q
- Guidance literature:
-
With
p-toluenesulfonic acid monohydrate;
In
acetone;
to Hg-complex in acetone was added p-toluenesulfonic acid monohydrate, refluxed for 5 h, cooled; solved was reduced, poured into H2O contg. NaHCO3, filtered, washed withwater, dried, recrystd. from hot EtOH; elem. anal.;
DOI:10.1021/ic010881q
- Guidance literature:
-
In
toluene;
byproducts: PPh3, C6H5CHO2C2H4; under N2 atm. to suspn. Ru complex in toluene aryl mercury derivative was added and heated to reflux for 6 h; soln. was cooled and filtered through Celite, solvent was removed in vacuo, residue was extd. with hexane, recrystn. from CH2Cl2-EtOH; elem. aNAL.;
DOI:10.1016/j.jorganchem.2007.02.029
