34824-58-3

Basic information

• Product Name: 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
• Synonyms: 2-(2-BROMOPHENYL)-1,3-DIOXOLANE;1-BROMO-2-(1,3-DIOXOLAN-2-YL)BENZENE;1,3-Dioxolane, 2-(2-bromophenyl)-;2-BROMOBENZALDEHYDE ETHYLENE ACETAL, 98+%;2-(2-Bromophenyl)-1,3-dioxolane,98%;2-Bromophenyldioxolane;2-Bromobenzaldehyde ethylene acetal, 1-Bromo-2-(1,3-dioxolan-2-yl)benzene;RARECHEM AL BP 0014
• CAS NO: 34824-58-3
• Molecular Formula: C₉H₉BrO₂
• Molecular Weight: 229.07
• EINECS: -0
• Product Categories: Aromatic Halides (substituted);Benzaldehyde;Adehydes, Acetals & Ketones;Bromine Compounds;Dioxanes & Dioxolanes;Dioxolanes
• Mol File: 34824-58-3.mol
• Article Data: 85

Chemical Properties

• Boiling Point: 126-127°C 5mm
• Flash Point: >230 °F
• Appearance: Clear colorless to pale yellow/Liquid
• Density: 1.535 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0103mmHg at 25°C
• Refractive Index: n20/D 1.569(lit.)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility: Difficult to mix in water.
• BRN: 1284374
• CAS DataBase Reference: 2-(2-BROMOPHENYL)-1,3-DIOXOLANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-BROMOPHENYL)-1,3-DIOXOLANE(34824-58-3)
• EPA Substance Registry System: 2-(2-BROMOPHENYL)-1,3-DIOXOLANE(34824-58-3)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 24/25
• WGK Germany: 2
• Hazardous Substances Data: 34824-58-3(Hazardous Substances Data)

Usage

Chemical Properties

Clear colorless to pale yellow liquid

Uses

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

InChI:InChI=1/C9H9BrO2/c10-8-4-2-1-3-7(8)9-11-5-6-12-9/h1-4,9H,5-6H2

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 107-07-3 2-chloro-ethanol 
• 7381-30-8 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane 
• 144-55-8 sodium hydrogencarbonate 
• 7732-18-5 water 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 95-46-5 2-methylphenyl bromide 
• 107-21-1 ethylene glycol 

Downstream Products

• 59259-01-7 2-<2-(1,3-dioxolanyl)>benzaldehyde 
• 152302-84-6 2-iodobenzaldehyde ethylene glycol ketal 
• 250649-15-1 4-(2-[1,3]dioxolan-2-yl-phenyl)-2,2,6,6-tetramethyl-3,6-dihydro-2H-pyran 
• 451478-48-1 2-(2-(2-[1,3]dioxol-2-ylphenyl)-4,5-dimethoxyphenyl)-4,4-dimethyl-4,5-dihydro[1,3]oxazole 
• 695816-45-6 (2-[1,3]dioxolan-2-yl-phenyl)phosphonic acid diethyl ester 
• 77446-38-9 2-lithiobenzaldehyde ethylene ketal 
• 133898-89-2 (+)-11-methyl-4,5,6,11-tetrahydrobenzo[6,7]cycloocta[1,2-b]-thiophen-6,11-imine 
• 100-51-6 benzyl alcohol 
• 1122103-20-1 C₁₄H₁₇BrO₃ 
• 1122103-21-2 C₁₆H₂₁BrO₃ 
• 1122103-22-3 C₁₇H₂₃BrO₃ 
• 1107595-20-9 C₂₇H₃₈ClO₂P 
• 132455-93-7 2-(2-trimethylstannylphenyl)-1,3-dioxolane 
• 50777-73-6 2-(ortho-diphenylphosphinophenyl)-1,3-dioxolane 

Relevant articles and documents

Conformational diastereoisomerism in tris-( 2-alkylimino) triphenylphosphines

A combination of one-dimensional, two-dimensional and nuclear Overhauser experiments allow complete NMR spectroscopic characterisation of the trifunctionalised triphenylphosphine, tris-(2-carboxaldehyde)triphenylphosphine 1. A single-crystal X-ray diffrac

Cobalt-Catalyzed Chemoselective Transfer Hydrogenative Cyclization Cascade of Enone-Tethered Aldehydes

The ligand-free Co-catalyzed chemoselective reductive cyclization cascade of enone-tethered aldehydes with i-PrOH as the environmentally benign hydrogen surrogate is developed by this study. Mechanistic studies disclosed that such a protocol is initiated

Annulative Morita-Baylis-Hillman reaction to synthesise chiral dibenzocycloheptanes

We describe the first metal-free and organocatalytic strategy to access highly functionalised dibenzocycloheptanesviaa phosphine-promoted annulative Morita-Baylis-Hillman (MBH) reaction. The method is manipulated to access to chiral dibenzocycloheptanes as well. This work represents a rare entry for the construction of seven-membered carbocyclesviathe MBH route. The realisation of several bioactive molecules possessing the dibenzocycloheptane core makes this an attractive strategy.