2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

Base Information

Chemical Name:2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile
CAS No.:1037718-54-9
Molecular Formula:C₁₈H₁₂N₆O
Molecular Weight:328.333
Hs Code.:

Synonyms:2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

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Technology Process of 2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

There total 4 articles about 2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 24173-36-2
4-azidobenzaldehyde

: 171082-32-9
2-dicyanomethylidene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran

: 1037718-54-9
2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

Guidance literature:: With acetic acid; In pyridine; at 20 ℃; for 24h;
DOI:10.1021/ja802883k

Reference yield:

: 623-04-1
4-aminobenzenemethanol

: 1037718-54-9
2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium nitrite; hydrogenchloride / water / 0.5 h / 0 °C

1.2: 1 h / 0 °C

2.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

3.1: pyridine; acetic acid / 39 h / 20 - 40 °C

With pyridine; hydrogenchloride; Dess-Martin periodane; acetic acid; sodium nitrite; In dichloromethane; water;
DOI:10.1016/j.tetlet.2013.03.133

Reference yield:

: 31499-54-4
4-azidobenzyl alcohol

: 1037718-54-9
2-{4-(4'-azidophenylethenyl)-3-cyano-5,5-dimethyl-5H-furan-2-ylidene}-malononitrile

Guidance literature:: Multi-step reaction with 2 steps

1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

2: pyridine; acetic acid / 39 h / 20 - 40 °C

With pyridine; Dess-Martin periodane; acetic acid; In dichloromethane;
DOI:10.1016/j.tetlet.2013.03.133