1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether

Base Information

• Chemical Name: 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether
• CAS No.: 152065-57-1
• Molecular Formula: C₃₀H₄₈O₉
• Molecular Weight: 552.706
• Mol file: 152065-57-1.mol

Synonyms:1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether

Chemical Property of 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether

There total 5 articles about 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

2-(2-bromoethoxy)tetrahydropyran (17739-45-6,59146-56-4) + 1,3,5-tris(hydroxymethyl)benzene (4464-18-0) → 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether (152065-57-1)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 144h; Heating;

DOI:10.1021/jo00079a013

Reference yield: 60.0%

2-(tetrahydropyran-2-yloxy)ethanol (2162-31-4) + 1,3,5-Tris(bromomethyl)benzene (18226-42-1) → 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether (152065-57-1)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 12h; Reflux;

DOI:10.1002/chem.200900329

Reference yield: 60.0%

→ 1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether (152065-57-1)

Guidance literature:

upstream raw materials:

2-(2-bromoethoxy)tetrahydropyran

1,3,5-tris(hydroxymethyl)benzene

benzene-1,3,5-tricarboxylic acid

1,3,5-tris-(methoxycarbonyl)benzene

Downstream raw materials:

1,3,5-tris[4'-(tosyloxy)-2'-oxa-1'-butyl]benzene

1,3,5-tris-(2-(3-(t-butoxycarbonyl)propylmalonyl)ethoxymethyl)benzene

1,3,5-tris-((2'-methylmalonyl)ethoxymethyl)benzene

1,3,5-tris-((2'-hydroxy)ethoxymethyl)benzene

Refernces

• 1、 -. "Method of synthesis of water soluble fullerene polyacids using a malonate reactant". Page/Page column 5; Sheet 11. . Retrieved 2008/06/13.
• 2、 An, Haoyun,Bradshaw, Jerald S.,Krakowiak, Krzysztof E.,Tarbet, Bryon J.,Dalley, N. Kent,et al.. "Novel Benzene-Bridged Macrobi- and Macrotricyclic Polyethers". . p. 7694 - 7699. Retrieved 2007/10/02.