Re(CO)3(bipyridyl)(CCPh)

Base Information

Chemical Name:Re(CO)3(bipyridyl)(CCPh)
CAS No.:234448-73-8
Molecular Formula:C₂₁H₁₃N₂O₃Re
Molecular Weight:527.553
Hs Code.:

Synonyms:Re(CO)3(bipyridyl)(CCPh)

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Chemical Property of Re(CO)3(bipyridyl)(CCPh)

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Technology Process of Re(CO)3(bipyridyl)(CCPh)

There total 4 articles about Re(CO)3(bipyridyl)(CCPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 468083-38-7
[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

: 536-74-3
phenylacetylene

: 234448-73-8
[Re(2,2'-bipyridine)(C_.ident.C-C₆H₅)]

Guidance literature:: With nBuLi; In tetrahydrofuran; hexane; to a soln. of phenylacetylene (0.040 mmol) in THF cooled to -78°Cwas added nBuLi (0.040 mmol) in hexane; the resulting soln. was added t o a soln. of Re-contg. compd. (0.040 mmol) in THF; stirring at room temp. for 15 min; the soln. was evapd. in vac., and the residue was extd. with toluene at 0°C; slow diffusion of hexane into a THF soln.; elem. anal.;
DOI:10.1021/ic020174c

Reference yield: 65.0%

: 56498-59-0,40231-87-6
Re(CO)3(2,2'-bipyridine)Br

: 536-74-3
phenylacetylene

: 234448-73-8
Re(CO)3(bipyridyl)(CCPh)

Guidance literature:: With thallium(I) hexafluorophosphate; In further solvent(s); byproducts: TlBr, (C2H5)NH(CH(CH3)2)PF6; treatment of rhenium compd. with acetylene deriv. in presence of thallium compd. in ethyldiisopropylamine for 15 h, TLC monitoring; chromy.;
DOI:10.1021/ic701406y

Reference yield: 30.0%

: 55658-96-3
tricarbonyl(2,2'-bipyridine)chlororhenium(I)

: 536-74-3
phenylacetylene

: 234448-73-8
[Re(2,2'-bipyridine)(C_.ident.C-C₆H₅)]

Guidance literature:: With silver triflate; triethylamine; In tetrahydrofuran; (N2); refluxing a mixt. of rhenium complex, silver salt, amine and alkyne in THF in the dark for 24 h; filtration, concn., column chromy (silica gel, CH2Cl2), recrystn. (acetone/Et2O); elem. anal.;
DOI:10.1016/S0022-328X(03)00010-X