[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

Base Information

Chemical Name:[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4
CAS No.:468083-38-7
Molecular Formula:C₁₇H₁₆N₂O₄Re*C₃₂H₁₂BF₂₄
Molecular Weight:1361.75
Hs Code.:

Synonyms:[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

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Technology Process of [Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

There total 2 articles about [Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 142939-90-0,97170-94-0
fac-tricarbonyl(2,2'-bipyridine)triflatorhenium(I)

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 468083-38-7
[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

Guidance literature:: In dichloromethane; byproducts: sodium triflate; CH2Cl2 was added to a mixt. of Re-contg. compd. (0.036 mmol) and NaBAr'4(0.036 mmol); then 5 equiv. of a ligand was added; stirring for 1 h; the soln. was filtered; diffusion of hexanes into soln. afforded the crystals of the complex; elem. anal.;
DOI:10.1021/ic020174c

Reference yield:

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: [Re(CO)3(2,2'-bipyridine)]CF₃SO₃

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 468083-38-7
[Re(2,2’-bipyridine)(CO)3(THF)][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:: In tetrahydrofuran; byproducts: CF3SO3Na; treatment of rhenium compd. with borate deriv. salt in THF;
DOI:10.1021/ic701406y

Reference yield: 68.0%

: 468083-38-7
[Re(tetrahydrofuran)(CO)3(2,2'-bipyridyl)]B(3,5-bis(trifluoromethyl)phenyl)4

: 536-74-3
phenylacetylene

: 234448-73-8
[Re(2,2'-bipyridine)(C_.ident.C-C₆H₅)]

Guidance literature:: With nBuLi; In tetrahydrofuran; hexane; to a soln. of phenylacetylene (0.040 mmol) in THF cooled to -78°Cwas added nBuLi (0.040 mmol) in hexane; the resulting soln. was added t o a soln. of Re-contg. compd. (0.040 mmol) in THF; stirring at room temp. for 15 min; the soln. was evapd. in vac., and the residue was extd. with toluene at 0°C; slow diffusion of hexane into a THF soln.; elem. anal.;
DOI:10.1021/ic020174c