8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

Base Information

Chemical Name:8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one
CAS No.:1235871-33-6
Molecular Formula:C₃₃H₂₅NO₅
Molecular Weight:515.565
Hs Code.:

Synonyms:8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

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Chemical Property of 8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

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Technology Process of 8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

There total 7 articles about 8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 957765-79-6
6-bromo-2,3-(methylenedioxy)benzoyl chloride

: 1235871-33-6
8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 20 °C

2: sodium hydride / N,N-dimethyl-formamide / 20 °C

3: palladium diacetate; tris-(o-tolyl)phosphine; silver carbonate / N,N-dimethyl-formamide / 155 °C

With palladium diacetate; sodium hydride; triethylamine; tris-(o-tolyl)phosphine; silver carbonate; In dichloromethane; N,N-dimethyl-formamide; 3: |Heck Reaction;
DOI:10.1016/j.bmcl.2012.09.097

Reference yield:

: 1235871-31-4
N-(5-([1,1'-biphenyl]-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromobenzo[d][1,3]dioxole-4-carboxamide

: 1235871-33-6
8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / N,N-dimethyl-formamide / 20 °C

2: palladium diacetate; tris-(o-tolyl)phosphine; silver carbonate / N,N-dimethyl-formamide / 155 °C

With palladium diacetate; sodium hydride; tris-(o-tolyl)phosphine; silver carbonate; In N,N-dimethyl-formamide; 2: |Heck Reaction;
DOI:10.1016/j.bmcl.2012.09.097

Reference yield:

: 72744-56-0
5-bromobenzo[d][1,3]dioxole-4-carboxylic acid

: 1235871-33-6
8-biphenyl-4-yl-9,10-dimethoxy-12-methyl-12H-1,3-dioxa-12-azacyclopenta[a]chrysene-13-one

Guidance literature:: Multi-step reaction with 4 steps

1: oxalyl dichloride / dichloromethane / 45 °C

2: triethylamine / dichloromethane / 20 °C

3: sodium hydride / N,N-dimethyl-formamide / 20 °C

4: palladium diacetate; tris-(o-tolyl)phosphine; silver carbonate / N,N-dimethyl-formamide / 155 °C

With oxalyl dichloride; palladium diacetate; sodium hydride; triethylamine; tris-(o-tolyl)phosphine; silver carbonate; In dichloromethane; N,N-dimethyl-formamide; 4: |Heck Reaction;
DOI:10.1016/j.bmcl.2012.09.097