mesityl-(3-nitro-phenyl)-methane

Base Information

• Chemical Name: mesityl-(3-nitro-phenyl)-methane
• CAS No.: 856192-10-4
• Molecular Formula: C₁₆H₁₇NO₂
• Molecular Weight: 255.316
• Mol file: 856192-10-4.mol

Synonyms:mesityl-(3-nitro-phenyl)-methane

Chemical Property of mesityl-(3-nitro-phenyl)-methane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mesityl-(3-nitro-phenyl)-methane

There total 1 articles about mesityl-(3-nitro-phenyl)-methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Nitrobenzyl chloride (619-23-8) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl-(3-nitro-phenyl)-methane (856192-10-4)

Guidance literature:

With aluminium trichloride;

DOI:10.1021/ja01584a038

Reference yield:

mesityl-(3-nitro-phenyl)-methane (856192-10-4) → 1,3,5-trimethyl-4-nitro-2-(3-nitro-benzyl)-benzene (856191-96-3)

Guidance literature:

With nitric acid; acetic anhydride; acetic acid; at -15 ℃;

DOI:10.1021/ja01584a038

Reference yield:

mesityl-(3-nitro-phenyl)-methane (856192-10-4) → N-benzenesulfonyl-N-[3-(3-methoxy-benzyl)-2,4,6-trimethyl-phenyl]-glycine

Guidance literature:

Multi-step reaction with 5 steps

1: acetic acid anhydride; acetic acid; HNO₃ / -15 °C

2: platinum; benzene / Hydrogenation

3: aqueous H₂SO₄ / Diazotization_.Erwaermen des Reaktionsprodukts mit wss. NaOH und Dimethylsulfat

4: N₂H_4.H₂O; Raney nickel / anschliessenden Erhitzen mit Benzolsulfonylchlorid in wss.NaHCO₃

5: potassium ethylate; ethanol

With ethanol; sulfuric acid; potassium ethoxide; nitric acid; acetic anhydride; nickel; hydrazine hydrate; acetic acid; platinum; benzene;

DOI:10.1021/ja01584a038

upstream raw materials:

3-Nitrobenzyl chloride

1,3,5-trimethyl-benzene

Downstream raw materials:

1,3,5-trimethyl-4-nitro-2-(3-nitro-benzyl)-benzene

3-(2,4,6-trimethyl-3-nitro-benzyl)-aniline

3-(2,4,6-trimethyl-3-nitro-benzyl)-anisole

benzenesulfonic acid-[3-(3-methoxy-benzyl)-2,4,6-trimethyl-anilide]