carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

Base Information

Chemical Name:carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)
CAS No.:156466-32-9
Molecular Formula:C₄₉H₃₆N₄O₂Os
Molecular Weight:903.05
Hs Code.:

Synonyms:carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

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Chemical Property of carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

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Technology Process of carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

There total 1 articles about carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: potassium hexachloroosmate(IV)

: 917-23-7,20998-75-8
5,10,15,20-tetraphenyl-21H,23H-porphine

: 110589-22-5
[OsO₂(meso-tetraphenylporphyrinato)]

: 156466-32-9
carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

Guidance literature:: With tetrahydrofuran; formic acid; carbon monoxide; In further solvent(s); refluxing K2OsCl6/formic acid under N2, 4h; evapn.; dissoln. in diethylenglycolmonomethyl ether; addn. of 1,2,4-trichlorobenzene and porphyrin; refluxing under CO, 16h; evapn.; dissoln. in THF; stirring, 20°C,2h; addn. of H2O; pptn.; filtration; washing (water); drying, 80°C; dissoln. in minimum amt. of CH2Cl2; chromy. (Al2O3, CH2Cl2, CH2Cl2/THF 9/1); elem. anal.;

Reference yield: 93.0%

: 156466-32-9
carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

: 1184-78-7
trimethylamine-N-oxide

: 110589-22-5
[OsO₂(meso-tetraphenylporphyrinato)]

Guidance literature:: In chlorobenzene; addn. of (CH3)3NO to Os complex soln.; refluxing, 10 min; evapn.; dissoln. in CH2Cl2; chromy. (Al2O3, CH2Cl2);

Reference yield: 79.0%

: 156466-32-9
carbonyl(tetrahydrofuran){5,10,15,20-tetraphenylporphyrinato}osmium(II)

: tetrasodium{carbonyl(aqua)(5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinato)osmium(II)}

Guidance literature:: With sodium hydroxide; water; In sulfuric acid; stirring Os complex soln. under N2, 20°C, 48h; addn. to water; neutralizing with NaOH; evapn.; dissoln. in the minimum amt. of water; addn. to acetone; pptn.; filtration; ultrafiltration; evapn.; elem. anal.;