1-bromo-4-(dodec-11-en-1-yloxy)benzene

Base Information

Chemical Name:1-bromo-4-(dodec-11-en-1-yloxy)benzene
CAS No.:162133-74-6
Molecular Formula:C₁₈H₂₇BrO
Molecular Weight:339.316
Hs Code.:

Synonyms:1-bromo-4-(dodec-11-en-1-yloxy)benzene

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Chemical Property of 1-bromo-4-(dodec-11-en-1-yloxy)benzene

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Technology Process of 1-bromo-4-(dodec-11-en-1-yloxy)benzene

There total 1 articles about 1-bromo-4-(dodec-11-en-1-yloxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 106-41-2
4-bromo-phenol

: 99828-63-4
dodec-11-ene bromide

: 162133-74-6
1-bromo-4-(dodec-11-en-1-yloxy)benzene

Guidance literature:: With potassium carbonate; In acetone; for 24h; Inert atmosphere; Reflux;
DOI:10.1194/jlr.D029207

Reference yield: 61.0%

: 162133-74-6
1-bromo-4-(dodec-11-en-1-yloxy)benzene

: (4-(dodec-11-en-1-yloxy)phenyl)boronic acid

Guidance literature:: 1-bromo-4-(dodec-11-en-1-yloxy)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 2h; Inert atmosphere;

With water; In tetrahydrofuran; hexane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1194/jlr.D029207

Reference yield:

: 162133-74-6
1-bromo-4-(dodec-11-en-1-yloxy)benzene

: (S)-4-((R,E)-1-hydroxy-13-[4-(4,4-difluoro-5,7-dimethyl-4-bora-3a,4a-diaza-s-indacen-3-yl)-phenoxy]tridec-2-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

1.2: 2 h / -78 - 20 °C / Inert atmosphere

1.3: 1 h / 20 °C / Inert atmosphere

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / methanol; toluene / 14 h / 20 °C / Inert atmosphere; Reflux

3.1: sodium methylate / methanol / 8 h / Reflux

4.1: hydrogen bromide / ethanol / 4 h / 0 - 20 °C

5.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 0.5 h / 90 °C

6.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 4 h / Inert atmosphere; Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; hydrogen bromide; sodium methylate; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; toluene; 2.1: |Suzuki-Miyaura Coupling;
DOI:10.1194/jlr.D029207