tetraphenylfluoroantimony(V)

Base Information

• Chemical Name: tetraphenylfluoroantimony(V)
• CAS No.: 426-77-7
• Molecular Formula: C₂₄H₂₀FSb
• Molecular Weight: 449.171
• Mol file: 426-77-7.mol

Synonyms:tetraphenylfluoroantimony(V)

Chemical Property of tetraphenylfluoroantimony(V)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylfluoroantimony(V)

There total 5 articles about tetraphenylfluoroantimony(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

sodium hexafluorosilicate + tetraphenylantimony(V) bromide (16894-69-2) → tetraphenylantimony fluoride (24696-67-1,426-77-7,853013-91-9)

Guidance literature:

In water; aq. soln. of NaSiF6 mixed with aq. soln. of antimony compd., pptd.; filtered off, washed (water), dried, recrystd. (toluene/alcohol);

DOI:10.1007/s11173-005-0006-5

Reference yield: 76.0%

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + tetraphenylstibonium hydroxide (13371-35-2,19638-16-5) → tetraphenylfluoroantimony(V) (426-77-7)

Guidance literature:

In not given;

DOI:10.1023/A:1024883328867

Reference yield: 67.0%

pentaphenylantimony (2170-05-0) + difluorotriphenyl-λ5-stibane (373-84-2,34716-90-0) → tetraphenylfluoroantimony(V) (426-77-7)

Guidance literature:

In toluene; 4 h, boiling water bath; solvent removing, residue re-crystn. (toluene-benzene);

upstream raw materials:

pentaphenylantimony

difluorotriphenyl-λ⁵-stibane

hydrogen fluoride

tetraphenylstibonium hydroxide

Downstream raw materials:

triphenylantimony

methyl cinnamate

iodotetraphenyl-λ⁵-stibane

Methyl cinnamate

Refernces

• 1、 Sharutin,Sharutina,Pakusina,Smirnova,Pushilin. "The structure of tetraarylantimony halides and tetraphenylantimony isothiocyanate". . p. 108 - 114. Retrieved 2008/10/09.
• 2、 Sharutin, V. V.,Sharutina, O. K.,Egorova, I. V.,Panova, L. P.. "Reactions of Pentaphenylbismuth and -antimony with Organoelement Compounds Ph3EX2 (E=Sb, Bi; X=F, Cl, Br, NO3)". . p. 318 - 319. Retrieved 2008/10/09.