Triphenylantimony

Base Information

• Chemical Name: Triphenylantimony
• CAS No.: 603-36-1
• Molecular Formula: C18H15Sb
• Molecular Weight: 353.067
• Hs Code.: 29310095
• European Community (EC) Number: 210-037-6
• NSC Number: 2844
• UNII: G1X1263AMM
• DSSTox Substance ID: DTXSID4052269
• Wikipedia: Triphenylstibine
• Wikidata: Q2347337
• Mol file: 603-36-1.mol

Synonyms:Triphenylantimony;603-36-1;Triphenylstibane;TRIPHENYLSTIBINE;Stibine, triphenyl-;Triphenylantimony(III);Trifenylstibin;Triphenyl stibine;Trifenylstibin [Czech];CCRIS 1300;NSC 2844;EINECS 210-037-6;BRN 3608108;UNII-G1X1263AMM;G1X1263AMM;DTXSID4052269;NSC-2844;4-16-00-01198 (Beilstein Handbook Reference);Triphenyl-stibane;NSC2844;Stibine, triphenyl;MFCD00003000;Antimony(III)triphenyl;WLN: R-SB-R&R;Triphenylantimony(III), 99%;C18-H15-Sb;DTXCID8030841;HVYVMSPIJIWUNA-UHFFFAOYSA-;Tox21_304035;BBL011483;STL146595;AKOS005721049;AC-4364;NCGC00357242-01;CAS-603-36-1;LS-146736;CS-0111156;FT-0696138;T0476;D92350;A832699;J-525128;Q2347337;Triphenylantimony(III), purum, >=99.0% (HPLC)

Chemical Property of Triphenylantimony

Chemical Property:

• Appearance/Colour: off-white powder
• Melting Point: 52-55 °C
• Refractive Index: 1.6948
• Boiling Point: 377 °C
• Flash Point: 109 °C
• PSA: 0.00000
• Density: 1.434 g/cm³
• LogP: 4.46040
• Storage Temp.: Store below +30°C.
• Solubility.: <0.001g/l
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 352.02119
• Heavy Atom Count: 19
• Complexity: 202

Purity/Quality:

99% ^*data from raw suppliers

Triphenylantimony >95.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn,N
• Statements: 20/22-51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: C1=CC=C(C=C1)[Sb](C2=CC=CC=C2)C3=CC=CC=C3
• Uses: Stibonium salts, cocatalyst in converting trienes to aromatics and hydroaromatics, react with nitricsulfuric acid to give trinitro derivatives, polymerization inhibitor, lubricating-oil additive.

Technology Process of Triphenylantimony

There total 169 articles about Triphenylantimony which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenylfluorostibine (6651-55-4) + phenyltrifluorosilane (368-47-8) → triphenylantimony (603-36-1) + silicon tetrafluoride (7783-61-1)

Guidance literature:

reflux for 3 d;

Reference yield: 99.0%

(C6H5)4SbSC6H5*0.06CHCl3 → biphenyl (92-52-4,1594-86-1) + diphenyl sulfide (139-66-2) + triphenylantimony (603-36-1) + diphenyldisulfane (882-33-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In neat (no solvent); thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;

DOI:10.1016/S0022-328X(00)83047-8

Reference yield: 98.1%

antimony(III) chloride (10025-91-9) + chlorobenzene (108-90-7) → triphenylantimony (603-36-1)

Guidance literature:

chlorobenzene; With cis-Octadecenoic acid; sodium; In toluene; at 30 - 40 ℃; for 2h; Inert atmosphere;

antimony(III) chloride; In toluene; at 110 ℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;

upstream raw materials:

methyl magnesium iodide

diethyl ether

diphenyl cadmium

triphenylbismuthane

Downstream raw materials:

phenyllithium

iodobenzene

stilbene

1,1-diphenyl-2-trimethylsilylethene

Refernces

• 1、 Innorta, G.,Foffani, A.,Torroni, S.,Serrazanetti, G.. "". . p. 189 - 196. Retrieved 1979.
• 2、 Duffin, Rebekah N.,Stephens, Liam J.,Blair, Victoria L.,Kedzierski, Lukasz,Andrews, Philip C.. "The thiol-based reduction of Bi(V) and Sb(V) anti-leishmanial complexes". . . Retrieved 2021/05/10.
• 3、 Matsumura, Mio,Dong, Yuqiang,Kakusawa, Naoki,Yasuike, Shuji. "Pd-catalyzed P-arylation of triarylantimony dicarboxylates with dialkyl H-phosphites without a base: Synthesis of arylphosphonates". . p. 130 - 133. Retrieved 2015/02/19.