Carbamic acid, 1-naphthalenyl-, 1-phenylethyl ester (9CI)

Base Information

• Chemical Name: Carbamic acid, 1-naphthalenyl-, 1-phenylethyl ester (9CI)
• CAS No.: 119994-28-4
• Molecular Formula: C19H17 N O2
• Molecular Weight: 291.34378
• Mol file: 119994-28-4.mol

Synonyms:Carbamicacid, 1-naphthalenyl-, 1-phenylethyl ester, (?à)-

Chemical Property of Carbamic acid, 1-naphthalenyl-, 1-phenylethyl ester (9CI)

Chemical Property:

• PSA: 41.82000
• LogP: 5.16310

Purity/Quality:

CARBAMIC ACID, 1-NAPHTHALENYL-, 1-PHENYLETHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamic acid, 1-naphthalenyl-, 1-phenylethyl ester (9CI)

There total 1 articles about Carbamic acid, 1-naphthalenyl-, 1-phenylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Phenylethanol (98-85-1,13323-81-4) + 1-Naphthyl isocyanate (86-84-0) → [1]naphthyl-carbamic acid-(1-phenyl-ethyl ester) (119994-28-4)

Guidance literature:

In toluene; for 72h; Product distribution; Ambient temperature; presence of chiral chelates of Cu⁽²⁺⁾, optical yield of unreacted alcohol;

Reference yield:

[1]naphthyl-carbamic acid-(1-phenyl-ethyl ester) (119994-28-4) + methyl iodide (74-88-4) → methyl naphthalen-1-yl carbamic acid 1-phenylethyl ester (1118917-21-7)

Guidance literature:

[1]naphthyl-carbamic acid-(1-phenyl-ethyl ester); With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 0.5h;

methyl iodide; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 24h;

DOI:10.1021/ja808959e

upstream raw materials:

1-Phenylethanol

1-Naphthyl isocyanate

Downstream raw materials:

methyl naphthalen-1-yl carbamic acid 1-phenylethyl ester

Refernces

• 1、 Potapov, V. M.,Panova, G. V.,Pekshueva, E. G.. "OPTICALLY ACTIVE CHELATE COMPOUNDS IN ASSYMMETRIC SYNTHESES I. KINETIC RESOLUTION OF RACEMATES OF α-METHYLBENZYL ALCOHOL AND OF α-METHYLBENZYLAMINE IN PRESENCE OF Cu(II) CHELATES". . p. 1027 - 1030. Retrieved 2007/10/02.