n-propyldiphenyltin hydride

Base Information

• Chemical Name: n-propyldiphenyltin hydride
• CAS No.: 153465-10-2
• Molecular Formula: C₁₅H₁₈Sn
• Molecular Weight: 317.018
• Mol file: 153465-10-2.mol

Synonyms:n-propyldiphenyltin hydride

Chemical Property of n-propyldiphenyltin hydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of n-propyldiphenyltin hydride

There total 2 articles about n-propyldiphenyltin hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

diphenyltin (1011-95-6) + propyl bromide (106-94-5) → n-propyldiphenyltin hydride (153465-10-2)

Guidance literature:

With n-butyllithium; water; diisopropylamine; In tetrahydrofuran; hexane; Petroleum ether; N2-atmosphere; stirring (0°C, 15 min), Sn-compd. addn. (-70°C), stirring (-50°C, 30 min), n-PrBr addn., petroleum ether addn. (0°C), H2O addn.; extg. (petroleum ether), washing (H2O), drying (MgSO4), evapn., distg.; elem. anal.;

DOI:10.1021/om960444x

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + C15H17ClSn → n-propyldiphenyltin hydride (153465-10-2)

Guidance literature:

In diethyl ether;

DOI:10.1139/cjc-2013-0504

Reference yield: 91.3%

n-propyldiphenyltin hydride (153465-10-2) + (E)-N-(3-chloropropyl)-2,2-dimethylpropan-1-imine (1609183-87-0) → (E)-N-(3-(diphenyl(propyl)stannyl)propyl)-2,2-dimethylpropan-1-imine

Guidance literature:

n-propyldiphenyltin hydride; With lithium diisopropyl amide; In tetrahydrofuran; at 0 ℃; for 0.0833333h; Schlenk technique;

(E)-N-(3-chloropropyl)-2,2-dimethylpropan-1-imine; In tetrahydrofuran; at 0 - 20 ℃; for 0.166667h; Schlenk technique;

DOI:10.1139/cjc-2013-0504

upstream raw materials:

diphenyltin

propyl bromide

lithium aluminium tetrahydride